ASTM D4056-21 - 1.12.2021
 
Significance and Use

5.1?Knowledge of the water content is important in lubrication, as large amounts of water can cause corrosion fatigue in steel bearings, and the complete absence of water can cause metal scuffing.

5.2?High water content has an accelerating effect on oxidation of lubricants, and can also contribute to foaming, especially at high altitude or temperature, or both.

 
1. Scope

1.1?This test method covers a procedure for estimating the equilibrium solubility of water and its vapor in hydrocarbon and aliphatic ester lubricants, at temperatures between 277 K and 373 K. The test method is limited to liquids of low to moderate polarity and hydrogen bonding, with predicted solubilities not over 1000 ppm by weight in hydrocarbons, or 30 000 ppm by weight in oxygenated compounds, at 298 K.

1.2?Specifically excluded are olefins, nitriles, nitro compounds, and alcohols.

1.3?This test method is recommended only for liquids not containing widely different chemical species. This excludes blends of esters with hydrocarbons, and lubricants containing detergents, dispersants, rust preventives, or load carrying additives.

1.4?The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.

1.5?This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.

1.6?This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

 
2. Referenced Documents

D94-25

Standard Test Methods for Saponification Number of Petroleum Products

D3238-22a

Standard Test Method for Calculation of Carbon Distribution and Structural Group Analysis of Petroleum Oils by the n-d-M Method (Includes all amendments and changes 12/13/2022).

D2502-24

Standard Test Method for Estimation of Mean Relative Molecular Mass of Petroleum Oils from Viscosity Measurements

D1298-24

Standard Test Method for Density, Relative Density, or API Gravity of Crude Petroleum and Liquid Petroleum Products by Hydrometer Method

D1218-21

Standard Test Method for Refractive Index and Refractive Dispersion of Hydrocarbon Liquids