ASTM D4057-22 - 1.5.2022
 
Significance and Use

4.1?Samples of petroleum and petroleum products are obtained for many reasons, including the determination of chemical and physical properties. These properties may be used for: calculating standard volumes; establishing product value; and often safety and regulatory reporting.

4.2?There are inherent limitations when performing any type of sampling, any one of which may affect the representative nature of the sample. As examples, a spot sample provides a sample from only one particular point in the tank, vessel compartment, or pipeline. In the case of running or all-level samples, the sample only represents the column of material from which it was taken.

4.3?Based on the product, and testing to be performed, this practice provides guidance on sampling equipment, container preparation, and manual sampling procedures for petroleum and petroleum products of a liquid, semi-liquid, or solid state, from the storage tanks, flowlines, pipelines, marine vessels, process vessels, drums, cans, tubes, bags, kettles, and open discharge streams into the primary sample container.

 
1. Scope

1.1?This practice covers procedures and equipment for manually obtaining samples of liquid petroleum and petroleum products, crude oils, and intermediate products from the sample point into the primary container are described. Procedures are also included for the sampling of free water and other heavy components associated with petroleum and petroleum products.

1.2?This practice also addresses the sampling of semi-liquid or solid-state petroleum products. For the sampling of green petroleum coke, see Practice D8145. For the sampling of calcined petroleum coke, see Practice D6970.

1.3?This practice provides additional specific information about sample container selection, preparation, and sample handling.

1.4?This practice does not cover sampling of electrical insulating oils and hydraulic fluids. If sampling is for the precise determination of volatility, use Practice D5842 (API MPMS Chapter 8.4) in conjunction with this practice. For sample mixing and handling, refer to Practice D5854 (API MPMS Chapter 8.3).

1.5?The procedures described in this practice may also be applicable in sampling most non-corrosive liquid industrial chemicals provided that all safety precautions specific to these chemicals are followed. Also, refer to Practice E300. The procedures described in this practice are also applicable to sampling liquefied petroleum gases and chemicals. Also refer to Practices D1265 and D3700. The procedure for sampling bituminous materials is described in Practice D140. Practice D4306 provides guidance on sample containers and preparation for sampling aviation fuel.

1.6?UnitsThe values stated in SI units are to be regarded as the standard. USC units are reflected in parentheses.

1.7?This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.

1.8?This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

 
2. Referenced Documents

D977-20(2026)e1

Standard Specification for Emulsified Asphalt (Includes all amendments and changes 2/19/2026).

D1265-23a

Standard Practice for Sampling Liquefied Petroleum (LP) Gases, Manual Method (Includes all amendments and changes 1/30/2024).

D1267-23

Standard Test Method for Gauge Vapor Pressure of Liquefied Petroleum (LP) Gases (LP-Gas Method)

D1298-24

Standard Test Method for Density, Relative Density, or API Gravity of Crude Petroleum and Liquid Petroleum Products by Hydrometer Method

D1657-22e1

Standard Test Method for Density or Relative Density of Light Hydrocarbons by Pressure Hydrometer (Includes all amendments and changes 3/14/2023).

D1838-21

Standard Test Method for Copper Strip Corrosion by Liquefied Petroleum (LP) Gases

D1856-25

Standard Test Method for Recovery of Asphalt from Solution by Abson Method

D2172-05

Standard Test Methods for Quantitative Extraction of Bitumen From Bituminous Paving Mixtures

D2622-26

Standard Test Method for Sulfur in Petroleum Products by Wavelength Dispersive X-ray Fluorescence Spectrometry

D3230-26

Standard Test Method for Salts in Crude Oil (Electrometric Method)

D3700-26

Standard Practice for Obtaining LPG Samples Using a Floating Piston Cylinder

D4006-22

Standard Test Method for Water in Crude Oil by Distillation

D664-24

Standard Test Method for Acid Number of Petroleum Products by Potentiometric Titration

D473-22

Standard Test Method for Sediment in Crude Oils and Fuel Oils by the Extraction Method

D445-24

Standard Test Method for Kinematic Viscosity of Transparent and Opaque Liquids (and Calculation of Dynamic Viscosity)

D5762-24

Standard Test Method for Nitrogen in Liquid Hydrocarbons, Petroleum and Petroleum Products by Boat-Inlet Chemiluminescence

D5191-22

Standard Test Method for Vapor Pressure of Petroleum Products and Liquid Fuels (Mini Method)

D5002-22

Standard Test Method for Density, Relative Density, and API Gravity of Crude Oils by Digital Density Analyzer

D4929-24

Standard Test Method for Determination of Organic Chloride Content in Crude Oil

D346-25

Standard Practice for Collection and Preparation of Coke Samples for Laboratory Analysis

D287-22

Standard Test Method for API Gravity of Crude Petroleum and Petroleum Products (Hydrometer/Method)

D323-20a

Standard Test Method for Vapor Pressure of Petroleum Products (Reid Method) (Includes all amendments and changes 12/9/2020).

D268-25

Standard Guide for Sampling and Testing Volatile Solvents and Chemical Intermediates for Use in Paint and Related Coatings and Material

D244-23

Standard Test Methods and Practices for Emulsified Asphalts

D5842-23

Standard Practice for Sampling and Handling of Fuels for Volatility Measurement

D5853-24

Standard Test Method for Pour Point of Crude Oils

D5854-25

Standard Practice for Mixing and Handling of Liquid Samples of Petroleum and Petroleum Products

D5863-22

Standard Test Methods for Determination of Nickel, Vanadium, Iron, and Sodium in Crude Oils and Residual Fuels by Flame Atomic Absorption Spectrometry

D6299-25a

Standard Practice for Applying Statistical Quality Assurance and Control Charting Techniques to Evaluate Analytical Measurement System Performance (Includes all amendments and changes 7/9/2025).

D6377-20

Standard Test Method for Determination of Vapor Pressure of Crude Oil: VPCRx (Expansion Method)

D6470-26

Standard Test Method for Salt in Crude Oils (Potentiometric Method)

D6560-22

Standard Test Method for Determination of Asphaltenes (Heptane Insolubles) in Crude Petroleum and Petroleum Products

D6822-25

Standard Test Method for Density, Relative Density, and API Gravity of Crude Petroleum and Liquid Petroleum Products by Thermohydrometer Method

D6849-22

Standard Practice for Storage and Use of Liquefied Petroleum Gases (LPG) in Sample Cylinders for LPG Test Methods

D7169-23

Standard Test Method for Boiling Point Distribution of Samples with Residues Such as Crude Oils and Atmospheric and Vacuum Residues by High Temperature Gas Chromatography

E300-03(2022)

Standard Practice for Sampling Industrial Chemicals

E882-10

Standard Guide for Accountability and Quality Control in the Chemical Analysis Laboratory

D4177-22e1

Standard Practice for Automatic Sampling of Petroleum and Petroleum Products (Includes all amendments and changes 3/24/2023).

D4294-24

Standard Test Method for Sulfur in Petroleum and Petroleum Products by Energy Dispersive X-ray Fluorescence Spectrometry

D4306-20

Standard Practice for Aviation Fuel Sample Containers for Tests Affected by Trace Contamination

D4377-00

Standard Test Method for Water in Crude Oils by Potentiometric Karl Fischer Titration

D4530-25

Standard Test Method for Determination of Carbon Residue (Micro Method)

D4629-24

Standard Test Method for Trace Nitrogen in Liquid Hydrocarbons by Syringe/Inlet Oxidative Combustion and Chemiluminescence Detection

D4807-05(2020)

Standard Test Method for Sediment in Crude Oil by Membrane Filtration

D4007-22

Standard Test Method for Water and Sediment in Crude Oil by the Centrifuge Method (Laboratory Procedure)

D4840-99(2018)e1

Standard Guide for Sample Chain-of-Custody Procedures (Includes all amendments and changes 8/22/2018).

D4928-24

Standard Test Method for Water in Crude Oils by Coulometric Karl Fischer Titration

D86-23ae2

Standard Test Method for Distillation of Petroleum Products and Liquid Fuels at Atmospheric Pressure (Includes all amendments and changes 11/4/2024).

D97-17b(2022)

Standard Test Method for Pour Point of Petroleum Products (Includes all amendments and changes 11/29/2022).

D140-01

Standard Practice for Sampling Bituminous Materials

D217-21a

Standard Test Methods for Cone Penetration of Lubricating Grease (Includes all amendments and changes 12/20/2021).