ASTM D4195-23 - 1.4.2023
 
Significance and Use

5.1?The performance of RO or NF membranes is strongly influenced by the composition of the feed solution. Overall salt rejection is dependent upon the ratio of monovalent to polyvalent ions as well as the sum total of ions present. The permeate flow rate of RO or NF devices is also dependent upon the sum total of the ions present and the operating temperature, pressure, and recovery rate. Analyses and measurements performed in this guide will provide vital data for salt rejection and permeate flow projections of RO or NF systems for specific feedwaters.

5.2?The recovery at which a RO or NF system can be safely operated is dependent upon the composition of the feed solution. The analyses and measurements performed in this guide will provide data for the calculation of the maximum recovery of a RO or NF system for a given feed solution.

5.3?The analyses and measurements performed in this guide will be of great assistance in determining the pretreatment requirements for a RO or NF system on a given feedwater.

 
1. Scope

1.1?This guide covers the analyses that should be performed on any given water sample if reverse osmosis (RO) or nanofiltration (NF) application is being considered. (See also Test Methods D511, D512, D513, D516, D858, D859, D888, D1068, D1179, D1253, D1293, D1889, D3352, D3370, D3561, D3867, D4189, D4194, and D4382.)

1.2?This guide is applicable to waters including brackish waters and seawaters but is not necessarily applicable to waste waters.

1.3?This is a guide only and should not be construed as a delineation of all ions known to exist in waters.

1.4?The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.

1.5?This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.

1.6?This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

 
2. Referenced Documents

D3370-25

Standard Practices for Sampling Water from Flowing Process Streams

D3561-16(2021)e1

Standard Test Method for Lithium, Potassium, and Sodium Ions in Brackish Water, Seawater, and Brines by Atomic Absorption Spectrophotometry (Includes all amendments and changes 12/22/2021).

D3867-16(2021)e1

Standard Test Methods for Nitrite-Nitrate in Water (Includes all amendments and changes 12/23/2021).

D859-16(2021)e1

Standard Test Method for Silica in Water (Includes all amendments and changes 12/6/2021).

D888-18

Standard Test Methods for Dissolved Oxygen in Water

D1068-15

Standard Test Methods for Iron in Water (Withdrawn 2024)

D1129-24

Standard Terminology Relating to Water

D858-17(2025)

Standard Test Methods for Manganese in Water

D512-23

Standard Test Methods for Chloride Ion In Water

D511-14(2021)e1

Standard Test Methods for Calcium and Magnesium In Water (Includes all amendments and changes 12/6/2021).

D4382-18

Standard Test Method for Barium in Water, Atomic Absorption Spectrophotometry, Graphite Furnace

D6161-19

Standard Terminology Used for Microfiltration, Ultrafiltration, Nanofiltration, and Reverse Osmosis Membrane Processes

APHA

Standard Methods for the Examination of Water and Wastewater, Sixteenth Edition, 1985, pp. 470-478, Part 427, Sulfite

D4194-23

Standard Test Methods for Operating Characteristics of Reverse Osmosis and Nanofiltration Devices

D513-16(2024)

Standard Test Methods for Total and Dissolved Carbon Dioxide in Water

D516-22

Standard Test Method for Sulfate Ion in Water

D857-17(2025)

Standard Test Method for Aluminum in Water

D1179-16(2021)e1

Standard Test Methods for Fluoride Ion in Water (Includes all amendments and changes 12/6/2021).

D1253-14(2021)e1

Standard Test Method for Residual Chlorine in Water (Includes all amendments and changes 12/6/2021).

D1293-18

Standard Test Methods for pH of Water

D1889-00

Standard Test Method for Turbidity of Water (Withdrawn 2007)

D4189-23

Standard Test Method for Silt Density Index (SDI) of Water

D3352-15

Standard Test Method for Strontium Ion in Brackish Water, Seawater, and Brines (Withdrawn 2024)

D2579-93e1

Standard Test Method for Total Organic Carbon in Water (Withdrawn 2002)