ASTM D4273-23 - 1.3.2023
 
Significance and Use

5.1?The primary hydroxyl content provides information about the relative reactivities of polyols in the urethane forming reaction with isocyanates.

 
1. Scope

1.1?Carbon-13 Nuclear Magnetic Resonance Spectroscopy?(13C NMR) measures the primary hydroxyl content of ethylene oxide (EO)-propylene oxide (PO) polyether polyols used in preparing flexible polyurethane foams. This method is best suited for polyether polyols with primary hydroxyl contents of 10 to 90 %.

1.2?The values stated in SI units are to be regarded as standard.

1.3?This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.

Note 1:?There is no known ISO equivalent to this standard.

1.4?This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

 
2. Referenced Documents

E386-90(1999)

Standard Practice for Data Presentation Relating to High-Resolution Nuclear Magnetic Resonance (NMR) Spectroscopy

E691-23

Standard Practice for Conducting an Interlaboratory Study to Determine the Precision of a Test Method

D883-25b

Standard Terminology Relating to Plastics (Includes all amendments and changes 11/20/2025).

E180-03

Standard Practice for Determining the Precision of ASTM Methods for Analysis and Testing of Industrial and Specialty Chemicals (Withdrawn 2009)