ASTM D4282-15(2022) - 1.5.2022
 
Significance and Use

5.1?This test method is useful in distinguishing between the potentially available free cyanide (total cyanide) and the free cyanide actually present.

5.2?This test method provides a convenient technique for making on-site free cyanide determinations.

 
1. Scope

1.1?This test method covers the determination of free cyanides in waters and wastewaters. Free cyanide is here defined as the cyanide which diffuses as cyanide (HCN), at room temperature, from a solution at pH 6.2

1.2?This test method does not include complexes that resist dissociation, such as hexacyanoferrates and gold cyanide, nor does it include thiocyanate and cyanohydrin.

1.3?This test method may be applied to water and wastewater samples containing free cyanide from 10 to 150 ?g/L. Greater concentrations may be determined by appropriate dilution.

1.4?This test method has been fully validated by collaborative testing as specified by Practice D2777.

1.5?The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.

1.6?This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. For specific hazard statements, see 8.6, 8.9, Section 9, and 12.2.1.

1.7?This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

 
2. Referenced Documents

D1193-24

Standard Specification for Reagent Water

D2777-21

Standard Practice for Determination of Precision and Bias of Applicable Test Methods of Committee D19 on Water

D3370-25

Standard Practices for Sampling Water from Flowing Process Streams

D5847-22

Standard Practice for Writing Quality Control Specifications for Standard Test Methods for Water Analysis

D3856-11

Standard Guide for Management Systems in Laboratories Engaged in Analysis of Water

D4210-89(1996)e1

Standard Practice for Intralaboratory Quality Control Procedures and a Discussion on Reporting Low-Level Data (Withdrawn 2002)

D5788-95(2024)

Standard Guide for Spiking Organics into Aqueous Samples

D5789-95

Standard Practice for Writing Quality Control Specifications for Standard Test Methods for Organic Constituents (Withdrawn 2002)

E275-08(2022)

Standard Practice for Describing and Measuring Performance of Ultraviolet and Visible Spectrophotometers

D1129-24

Standard Terminology Relating to Water

D1192-98

Standard Guide for Equipment for Sampling Water and Steam in Closed Conduits (Withdrawn 2003)