ASTM D4301-05(2019) - 1.10.2019
 
Significance and Use

5.1 The presence of residual chlorine in epoxy resins is deleterious to final product properties. This test method has been found to be applicable to resins or ethers with chlorine contents ranging from 50 ppm to 35 % by weight. Other halogen compounds react with the reagent but are distinguished from chlorine by the final potentiometric titration. Epoxy and other functional groups will consume reagent but do not affect the results.

 
1. Scope

1.1 This test method describes a procedure for the determination of total chlorine in epoxy resins and glycidyl ethers.

1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.

1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. For specific hazard statements, see Section 8.

1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

 
2. Referenced Documents

OSHA Regulations, 29 CFR

paragraphs 1910.1000 and 1910.1200 A suitable mechanical holder is available from the Gardner Laboratory, Inc., 5521 Landy Lane, Washington, DC, Item 660.

D6440-10(2025)

Standard Terminology Relating to Hydrocarbon Resins

D1193-24

Standard Specification for Reagent Water

E691-23

Standard Practice for Conducting an Interlaboratory Study to Determine the Precision of a Test Method