ASTM D4517-15(2023) - 1.4.2023
 
Significance and Use

5.1?Control of silica in boiler feedwater and boiler water is necessary to minimize the formation of scale-forming silicates that decrease heat transfer in the boiler. Volatilization and carryover of silica with the steam may cause hard, glassy siliceous deposits to form on turbine blades that reduce turbine efficiency.

5.2?Colloidal silica that is not removed by boiler water pretreatment processes may be solubilized in the boiler and thus contribute to the dissolved silica concentration in the boiler. Both dissolved and total silica are of interest.

 
1. Scope

1.1?This test method covers the determination of total silica in water.

1.2?This test method is applicable in the range from 25 ?g/L to 250 ?g/L of silica as SiO2. Higher concentrations may be determined by decreasing the aliquot volume (see Note 6). Concentration range should not be extended by dilution.

1.3?This test method determines total silica, and does not distinguish between soluble and insoluble forms.

1.4?This test method was tested on reagent water only. It is the user's responsibility to assure the validity of the test method for waters of other matrices.

1.5?The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.

1.6?This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.

1.7?This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

 
2. Referenced Documents

D1066-18e1

Standard Practice for Sampling Steam (Includes all amendments and changes 12/31/2018).

D1129-13(2020)e2

Standard Terminology Relating to Water (Includes all amendments and changes 2/14/2024).

D1192-98

Standard Guide for Equipment for Sampling Water and Steam in Closed Conduits (Withdrawn 2003)

D1193-06(2018)

Standard Specification for Reagent Water

D2777-21

Standard Practice for Determination of Precision and Bias of Applicable Test Methods of Committee D19 on Water

D3370-18

Standard Practices for Sampling Water from Flowing Process Streams

D859-16(2021)e1

Standard Test Method for Silica in Water (Includes all amendments and changes 12/6/2021).

D5847-22

Standard Practice for Writing Quality Control Specifications for Standard Test Methods for Water Analysis

D4453-17

Standard Practice for Handling of High Purity Water Samples

D5810-96(2021)

Standard Guide for Spiking into Aqueous Samples

D3919-15

Standard Practice for Measuring Trace Elements in Water by Graphite Furnace Atomic Absorption Spectrophotometry