ASTM D4814-01 - 10.11.2001
 
1. Scope

1.1 This specification guides in establishing requirements of automotive fuels for ground vehicles equipped with spark-ignition engines.

1.2 This specification describes various characteristics of automotive fuels for use over a wide range of operating conditions. It provides for a variation of the volatility and water tolerance of automotive fuel in accordance with seasonal climatic changes at the locality where the fuel is used. For the period May 1 through September 15, the maximum vapor pressure limits issued by the U.S. Environmental Protection Agency (EPA) are specified for each geographical area except Alaska and Hawaii. Variation of antiknock index with seasonal climatic changes and altitude is discussed in . This specification neither necessarily includes all types of fuels that are satisfactory for automotive vehicles, nor necessarily excludes fuels that can perform unsatisfactorily under certain operating conditions or in certain equipment. The significance of each of the properties of this specification is shown in Appendix X1.

1.3 The spark-ignition engine fuels covered in this specification are gasoline and its blends with oxygenates such as alcohols and ethers. This specification does not apply to fuels that contain an oxygenate as the primary component, such as Fuel Methanol (M85). The concentrations and types of oxygenates are not specifically limited in this specification. However, depending on oxygenate type, as oxygenate content increases above some threshold level, the likelihood for vehicle problems also increases. The composition of both unleaded and leaded fuel is limited by economic, legal, and technical consideration, but their properties, including volatility, are defined by this specification. In addition, the composition of unleaded fuel is subject to the rules, regulations, and Clean Air Act waivers of the U.S. Environmental Protection Agency (EPA). With regard to fuel properties, including volatility, this specification can be more or less restrictive than the EPA rules, regulations, and waivers. Refer to Appendix X3 for discussions of EPA rules relating to fuel volatility, lead and phosphorous contents, deposit control additive certification, and use of oxygenates in blends with unleaded gasoline. Contact EPA for the latest versions of the rules and additional requirements.

1.4 This specification does not address the emission characteristics of reformulated spark-ignition engine fuel. Reformulated spark-ignition engine fuel is required in some areas to lower emissions from automotive vehicles, and its characteristics are described in the research report on reformulated spark-ignition engine fuel. However, in addition to the legal requirements found in this research report, reformulated spark-ignition engine fuel should meet the performance requirements found in this specification.

1.5 This specification represents a description of automotive fuel as of the date of publication. The specification is under continuous review, which can result in revisions based on changes in fuel, automotive requirements, or test methods, or a combination thereof. All users of this specification, therefore, should refer to the latest edition.

Note 1--If there is any doubt as to the latest edition of Specification D4814, contact ASTM Headquarters.

1.6 Tests applicable to gasoline are not necessarily applicable to its blends with oxygenates. Consequently, the type of fuel under consideration must first be identified in order to select applicable tests. Test Method D4815 provides a procedure for determining oxygenate concentration in mass percent. Test Method D4815 also includes procedures for calculating mass oxygen content and oxygenate concentration in volume percent. provides a procedure for calculating the mass oxygen content of a fuel using measured oxygenate type, oxygenate concentration in volume percent, and measured density or relative density of the fuel.

1.7 The following applies to all specified limits in this standard: For purposes of determining conformance with these specifications, an observed value or a calculated value shall be rounded "to the nearest unit" in the right-most significant digit used in expressing the specification limit, in accordance with the rounding method of Practice E 29. The use of a trailing decimal point in a limit indicates that the digit preceding the decimal point is a significant digit.

1.8 The values stated in SI units are the standard, except when other units are specified by federal regulation. Values given in parentheses are provided for information only.

Note 2--Many of the values shown in Table 1 were originally developed using U.S. customary units and were subsequently soft-converted to SI values. As a result, conversion of the SI values will sometimes differ slightly from the U.S. customary values shown because of round-off. In some cases, federal regulations specify non-SI units.

1.9 The following safety hazard caveat pertains only to the test method portion, Annex A1 of this specification. This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

 
2. Referenced Documents

D4815-22

Standard Test Method for Determination of MTBE, ETBE, TAME, DIPE, tertiary-Amyl Alcohol and C1 to C4 Alcohols in Gasoline by Gas Chromatography

D4953-26

Standard Test Method for Vapor Pressure of Gasoline and Gasoline-Oxygenate Blends (Dry Method)

D5059-26

Standard Test Methods for Lead and Manganese in Gasoline by X-Ray Fluorescence Spectroscopy

D5188-23

Standard Test Method for Vapor-Liquid Ratio Temperature Determination of Fuels (Evacuated Chamber and Piston Based Method)

D5191-22

Standard Test Method for Vapor Pressure of Petroleum Products and Liquid Fuels (Mini Method)

D5453-25

Standard Test Method for Determination of Total Sulfur in Light Hydrocarbons, Spark Ignition Engine Fuel, Diesel Engine Fuel, and Engine Oil by Ultraviolet Fluorescence

D5482-26

Standard Test Method for Vapor Pressure of Petroleum Products and Liquid Fuels (Mini Method—Atmospheric)

D5500-20a

Standard Test Method for Vehicle Evaluation of Unleaded Automotive Spark-Ignition Engine Fuel for Intake Valve Deposit Formation (Includes all amendments and changes 6/3/2020).

D5598-20

Standard Test Method for Evaluating Unleaded Automotive Spark-Ignition Engine Fuel for Electronic Port Fuel Injector Fouling

D5599-22

Standard Test Method for Determination of Oxygenates in Gasoline by Gas Chromatography and Oxygen Selective Flame Ionization Detection

D5842-23

Standard Practice for Sampling and Handling of Fuels for Volatility Measurement

D5845-21

Standard Test Method for Determination of MTBE, ETBE, TAME, DIPE, Methanol, Ethanol and tert-Butanol in Gasoline by Infrared Spectroscopy

D5854-25

Standard Practice for Mixing and Handling of Liquid Samples of Petroleum and Petroleum Products

D6378-22

Standard Test Method for Determination of Vapor Pressure (VPX) of Petroleum Products, Hydrocarbons, and Hydrocarbon-Oxygenate Mixtures (Triple Expansion Method)

D6469-24

Standard Guide for Microbial Contamination in Fuels and Fuel Systems

D6920-13

Standard Test Method for Total Sulfur in Naphthas, Distillates, Reformulated Gasolines, Diesels, Biodiesels, and Motor Fuels by Oxidative Combustion and Electrochemical Detection (Withdrawn 2018)

D7039-24

Standard Test Method for Sulfur in Gasoline, Diesel Fuel, Jet Fuel, Kerosine, Biodiesel, Biodiesel Blends, and Gasoline-Ethanol Blends by Monochromatic Wavelength Dispersive X-ray Fluorescence Spectrometry

D7220-22

Standard Test Method for Sulfur in Automotive, Heating, and Jet Fuels by Monochromatic Energy Dispersive X-ray Fluorescence Spectrometry

D7667-21

Standard Test Method for Determination of Corrosiveness to Silver by Automotive Spark-Ignition Engine Fuel—Thin Silver Strip Method

D7671-21

Standard Test Method for Corrosiveness to Silver by Automotive Spark–Ignition Engine Fuel–Silver Strip Method

D7757-22

Standard Test Method for Silicon in Gasoline and Related Products by Monochromatic Wavelength Dispersive X-ray Fluorescence Spectrometry

E29-22

Standard Practice for Using Significant Digits in Test Data to Determine Conformance with Specifications

16 CFR Part 306

Automotive Fuel Ratings, Certification and Posting Available from U.S. Government Printing Office, Superintendent of Documents, 732 N. Capitol St., NW, Mail Stop: SDE, Washington, DC 20401.

CFR 40

Code of Federal Regulations

CCR Title 17, §60100-§60114

California Code of Regulations Available from Barclays, 50 California Street, San Francisco, CA 94111.

API Recommended Practice 1640

Product Quality in Light Product Storage and Handling Operations Available from American Petroleum Institute (API), 1220 L. St., NW, Washington, DC 20005-4070, http://www.api.org/pubs.

CRC Report No. 638

Intermediate-Temperature Volatility Program, 2003 Available from Coordinating Research Council (CRC), 5755 North Point Pkwy #265, Alpharetta, GA 30022, http://www.crcao.org.

CRC Report No. 666

Diesel Fuel Storage and Handling Guide, September 2014

D86-23ae2

Standard Test Method for Distillation of Petroleum Products and Liquid Fuels at Atmospheric Pressure (Includes all amendments and changes 11/4/2024).

D130-26

Standard Test Method for Corrosiveness to Copper from Petroleum Products by Copper Strip Test

D287-22

Standard Test Method for API Gravity of Crude Petroleum and Petroleum Products (Hydrometer/Method)

D381-25

Standard Test Method for Gum Content in Fuels by Jet Evaporation

D439-89

Specification for Automotive Gasoline (Withdrawn 1990)

D525-12a(2025)

Standard Test Method for Oxidation Stability of Gasoline (Induction Period Method) (Includes all amendments and changes 12/24/2025).

D1266-18

Standard Test Method for Sulfur in Petroleum Products (Lamp Method) (Withdrawn 2025)

D1298-24

Standard Test Method for Density, Relative Density, or API Gravity of Crude Petroleum and Liquid Petroleum Products by Hydrometer Method

D2622-26

Standard Test Method for Sulfur in Petroleum Products by Wavelength Dispersive X-ray Fluorescence Spectrometry

D2699-26

Standard Test Method for Research Octane Number of Spark-Ignition Engine Fuel

D2700-26b

Standard Test Method for Motor Octane Number of Spark-Ignition Engine Fuel (Includes all amendments and changes 7/13/2026).

D2885-21(2025)e1

Standard Test Method for Determination of Octane Number of Spark-Ignition Engine Fuels by On-Line Direct Comparison Technique (Includes all amendments and changes 3/27/2026).

D3120-25

Standard Test Method for Trace Quantities of Sulfur in Light Liquid Petroleum Hydrocarbons by Oxidative Microcoulometry

D3231-25

Standard Test Method for Phosphorus in Gasoline

D3237-22

Standard Test Method for Lead in Gasoline by Atomic Absorption Spectroscopy

D3341-16

Standard Test Method for Lead in Gasoline—Iodine Monochloride Method (Withdrawn 2022)

D3831-22

Standard Test Method for Manganese in Gasoline By Atomic Absorption Spectroscopy

D4052-22

Standard Test Method for Density, Relative Density, and API Gravity of Liquids by Digital Density Meter

D4057-22

Standard Practice for Manual Sampling of Petroleum and Petroleum Products

D4175-24e2

Standard Terminology Relating to Petroleum Products, Liquid Fuels, and Lubricants (Includes all amendments and changes 6/9/2026).

D4176-22e1

Standard Test Method for Free Water and Particulate Contamination in Distillate Fuels (Visual Inspection Procedures) (Includes all amendments and changes 6/30/2025).

D4177-22e1

Standard Practice for Automatic Sampling of Petroleum and Petroleum Products (Includes all amendments and changes 3/24/2023).

D4306-20

Standard Practice for Aviation Fuel Sample Containers for Tests Affected by Trace Contamination

D4806-25

Standard Specification for Denatured Fuel Ethanol