ASTM D4815-99 - 10.11.1999
 
1. Scope

1.1 This test method is designed for the determination of ethers and alcohols in gasolines by gas chromatography. Specific compounds determined are: methyl tert -butylether (MTBE), ethyl tert -butylether (ETBE), tert -amylmethylether (TAME), diisopropylether (DIPE), methanol, ethanol, isopropanol, -propanol, isobutanol, tert -butanol, sec butanol, -butanol, and tert -pentanol ( tert -amylalcohol).

1.2 Individual ethers are determined from 0.1 to 20.0 mass percent. Individual alcohols are determined from 0.1 to 12.0 mass percent. Equations used to convert to mass percent oxygen and to volume % of individual compounds are provided.

1.3 Alcohol-based fuels such as M-85 and E-85, MTBE product, ethanol product and denatured alcohol are specifically excluded from this method. The methanol content of M-85 fuel is considered beyond the operating range of the system.

1.4 Benzene, while detected, cannot be quantified using this test method and must be analyzed by alternate methodology (Test Method D3606 or D4420).

1.5 SI (metric) units are preferred and used throughout this standard. Alternate units, in common usage, are also provided to increase clarity and aid the users of this test method.

1.6 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use/i.

 
2. Referenced Documents

D1298-24

Standard Test Method for Density, Relative Density, or API Gravity of Crude Petroleum and Liquid Petroleum Products by Hydrometer Method

D1744-13

Standard Test Method for Determination of Water in Liquid Petroleum Products by Karl Fischer Reagent (Withdrawn 2016)

D3606-26

Standard Test Method for Determination of Benzene and Toluene in Spark Ignition Fuels by Gas Chromatography

D4052-22

Standard Test Method for Density, Relative Density, and API Gravity of Liquids by Digital Density Meter

D4057-22

Standard Practice for Manual Sampling of Petroleum and Petroleum Products

D4307-17(2021)

Standard Practice for Preparation of Liquid Blends for Use as Analytical Standards

D4420-94(1999)e1

Standard Test Method for Determination of Aromatics in Finished Gasoline by Gas Chromatography (Withdrawn 2004)

D5599-22

Standard Test Method for Determination of Oxygenates in Gasoline by Gas Chromatography and Oxygen Selective Flame Ionization Detection

D6708-24

Standard Practice for Statistical Assessment and Improvement of Expected Agreement Between Two Test Methods that Purport to Measure the Same Property of a Material