ASTM D4856-11(2016) - 1.10.2016
 
Significance and Use

5.1 Sulfuric acid is used in the manufacture of fertilizer, explosives, dyestuffs, other acids, parchment paper, glue, lead acid batteries, textiles, etc., and in the pickling of metals.

5.2 This test method has been found to be satisfactory in the measurement of sulfuric acid for comparison with relevant occupational exposure limits.

 
1. Scope

1.1 This ion chromatographic test method describes the determination of sulfuric acid mist in air samples collected from workplace atmospheres on a mixed cellulose ester (MCE) filter.

Note 1: Other filter types such as quartz fiber, polytetrafluoroethylene (PTFE), and polyvinyl chloride (PVC) filters are also suitable.

1.2 The lower detection limit of this test method is 0.001 mg/sample or 0.017 mg/m3 of sulfuric acid (H2SO4) mist in 60 L of air sampled at 1 L/min.

1.3 This test method is subject to interference from soluble and partially soluble sulfate salts. Other sulfur-containing compounds can be oxidized to sulfate and also interfere.

1.4 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.

1.5 No detailed instrument operating instructions are provided because of differences among various makes and models of ion chromatography (IC) systems. Instead, the analyst shall follow the instructions provided by the manufacturer of the particular instrument, analytical column, and suppressors used.

1.6 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. For specific precautionary statements, see Section 9.

 
2. Referenced Documents

ISO648

Laboratory glasswareOne Mark pipettes Available from American National Standards Institute (ANSI), 25 W. 43rd St., 4th Floor, New York, NY 10036, http://www.ansi.org.

Air qualityParticle size fraction definitions for health-related sampling

ISO 1042

Workplace atmospheresGeneral requirements for the performance of procedures for the measurement of chemical agents Available from European Committee for Standardization (CEN), Avenue Marnix 17, B-1000, Brussels, Belgium, http://www.cen.eu.

Workplace atmospheresTerminology

Workplace atmospheresProcedures for measuring metals and metalloids in airborne particlesRequirements and test methods

D1193-24

Standard Specification for Reagent Water

D1356-20a

Standard Terminology Relating to Sampling and Analysis of Atmospheres (Includes all amendments and changes 9/7/2020).

D1914-95(2022)

Standard Practice for Conversion Units and Factors Relating to Sampling and Analysis of Atmospheres

D4327-17(2025)

Standard Test Method for Anions in Water by Suppressed Ion Chromatography

E200-23

Standard Practice for Preparation, Standardization, and Storage of Standard and Reagent Solutions for Chemical Analysis