ASTM D4861-00 - 10.3.2000
 
1. Scope

1.1 This practice describes the sampling of atmospheres for a variety of common pesticides and polychlorinated biphenyls (PCBs) and provides guidance on the selection of appropriate analytical measurement methods.

1.2 A complete listing of pesticides and other semivolatile organic chemicals for which this practice has been tested is shown in Table 1.

1.3 This practice is based on the adsorption of chemicals from air on polyurethane foam (PUF) or a combination of PUF and granular sorbent.

1.4 This practice is applicable to multicomponent atmospheres, 0.001 to 50 [mu]g/m concentrations, and 4 to 24-h sampling periods. The limit of detection will depend on the nature of the analyte and the length of the sampling period.

1.5 The analytical method(s) recommended will depend on the specific chemical(s) sought, the concentration level, and the degree of specificity required.

1.6 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. For specific hazards statements, see Notes 3 and A1.1.

 
2. Referenced Documents

D1193-24

Standard Specification for Reagent Water

40 CFR 136

EPA Organic Chemical Analysis of Municipal and Industrial Wastewater Also available at http://ecfr.gpoaccess.gov/cgi/t/text/text-idx?c=ecfr&tpl=/ecfrbrowse/Title40/40cfr136_main_02.tpl

E355-96(2021)e1

Standard Practice for Gas Chromatography Terms and Relationships (Includes all amendments and changes 4/28/2021).

D4185-23

Standard Test Method for Measurement of Metals in Workplace Atmospheres by Flame Atomic Absorption Spectrophotometry

D3687-19

Standard Test Method for Analysis of Organic Compound Vapors Collected by the Activated Charcoal Tube Adsorption Method

D3686-20

Standard Practice for Sampling Atmospheres to Collect Organic Compound Vapors (Activated Charcoal Tube Adsorption Method)

D1356-20a

Standard Terminology Relating to Sampling and Analysis of Atmospheres (Includes all amendments and changes 9/7/2020).

NIOSH Manual of Analytical Methods Also available at http://www.cdc.gov/niosh/docs/2003-154/