ASTM D4874-95 - 1.1.2001
 
1. Scope

1.1 This test method is a standard laboratory procedure for generating aqueous leachate from materials using a column apparatus. It provides a leachate suitable for organic analysis of semivolatile and nonvolatile compounds as well as inorganic analyses.

1.2 The column apparatus is designed and constructed of materials chosen to enhance the leaching of low concentrations of semivolatile and nonvolatile organic constituents as well as to maximize the leaching of metallic species from the solid. Analysis of column effluent provides information on the leaching characteristics of material under the conditions used in the test.

1.3 This test method provides for the passage of an aqueous fluid through materials of known mass in a saturated up-flow mode.

1.4 It is intended that the sample used in the procedure be physically, chemically, and biologically representative of the material.

1.5 This test method does not produce results that can be used as the sole basis for (1) engineering design of a disposal site, or (2) the characterization of wastes based on their leaching characteristics.

1.6 This test method has the following limitations

1.6.1 Maximum particle size is 10 mm (0.4 in.). Particle size reduction is not recommended. Large-diameter material (cinders, rocks, and so forth) should be removed prior to packing the column to ensure adequate compaction.

1.6.2 Test materials containing densely immiscible organic material may result in phase separation and lead to column plugging.

1.6.3 This test method does not differentiate between dissolved constituents and sub-70-µm particulates that pass through the pores of the end plates.

1.6.4 This test method is not applicable to the leachability characterization of materials with regard to volatile compounds.

1.6.5 This test method is not applicable to the characterization of materials that dissolve in water to a degree that significantly impacts the void volume in the column or the determination of the specific gravity of the material.

1.7 Application of this test method to materials with initial low permeability, or to those that lose permeability over the course of the test, may result in long testing periods.

1.8 The values stated in SI units are to be regarded as the standard. The values given in parentheses are in approximate inch-pound equivalents.

1.9 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

 
2. Referenced Documents

D854-23

Standard Test Methods for Specific Gravity of Soil Solids by the Water Displacement Method

C819-77

Test Method for Specific Surface Area of Carbon or Graphite (Withdrawn 1987)

D422-63(1998)

Standard Test Method for Particle-Size Analysis of Soils

D698-12(2021)

Standard Test Methods for Laboratory Compaction Characteristics of Soil Using Standard Effort (12,400 ft-lbf/ft3 (600 kN-m/m3))

D1129-24

Standard Terminology Relating to Water

D2216-19

Standard Test Methods for Laboratory Determination of Water (Moisture) Content of Soil and Rock by Mass

D1888-78

Methods of Test for Particulate and Dissolved Matter in Water (Withdrawn 1989)

D1498-14(2022)e1

Standard Test Method for Oxidation-Reduction Potential of Water (Includes all amendments and changes 12/7/2022).

D1293-18

Standard Test Methods for pH of Water

D1125-23

Standard Test Methods for Electrical Conductivity and Resistivity of Water

D2434-26

Standard Test Methods for Laboratory Measurement of Hydraulic Conductivity of Coarse-Grained Soils

D4253-16

Standard Test Methods for Maximum Index Density and Unit Weight of Soils Using a Vibratory Table

E691-23

Standard Practice for Conducting an Interlaboratory Study to Determine the Precision of a Test Method

D3370-25

Standard Practices for Sampling Water from Flowing Process Streams

D3694-96(2024)

Standard Practices for Preparation of Sample Containers and for Preservation of Organic Constituents