ASTM D5071-06(2021) - 1.12.2021
 
Significance and Use

4.1?Materials made from photodegradable plastics are intended to deteriorate rapidly when exposed to solar radiation, oxygen, heat, moisture and other degrading elements of the weather. This practice is used for evaluating the photodegradability of plastics when exposed in an apparatus that produces simulated daylight (1,2)6 and controlled temperature and moisture. The exposure used in this practice is not intended to simulate the deterioration caused by localized weather phenomena such as atmospheric pollution, biological attack, and salt water exposure. There can be no positive correlation of exposure results between this and other laboratory weathering devices.

4.2?Variations in results can be expected when operating conditions are varied within the accepted limits of this practice. Therefore, all test results using this practice must be accompanied by the specific operating conditions required in Section 9. Refer to Practice G151 for detailed information on the caveats applicable to use of results obtained in accordance with this practice.

4.3?The results of laboratory exposure cannot be directly extrapolated to estimate absolute rate of deterioration by the environment because the acceleration factor is material dependent and can be significantly different for each material and for different formulations of the same material. However, exposure of a similar material of known outdoor performance, a control, at the same time as the test specimens allows comparison of the durability relative to that of the control under the test conditions. Evaluation in terms of relative durabilities also greatly improves the agreement in test results among different laboratories (3).

4.4?Test results will depend on the care that is taken to operate the equipment in accordance with Practice G155. Significant factors include regulation of line voltage, freedom from salt or other deposits from water, temperature and humidity control and condition and age of the burners and filters.

Note 2:?Additional information on sources of variability and on strategies for addressing variability in the design, execution and data analysis of laboratory accelerated exposure tests is found in Guide G141.

4.5?Before proceeding with this practice, it is common practice to reference the specifications of the material being tested. Any test specimen preparation, conditioning, dimensions, or testing parameters, or combination thereof, covered in the material specification shall take precedence over those mentioned in this practice. If there are no material specifications, then the default conditions apply.

 
1. Scope

1.1?This practice covers specific procedures and test conditions that are applicable for xenon arc exposure of photodegradable plastics conducted in accordance with Practices G151 and G155. This practice also covers the preparation of test specimens, the test conditions best suited for photodegradable plastics, and the evaluation of test results.

1.2?This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.

Note 1:?This practice is technically equivalent to ISO 4892-2 and Practice D2565 which cover xenon arc exposures of plastics intended for long term use in outdoor applications.

1.3?This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

 
2. Referenced Documents

E691-23

Standard Practice for Conducting an Interlaboratory Study to Determine the Precision of a Test Method

G113-22

Standard Terminology Relating to Natural and Artificial Weathering Tests of Nonmetallic Materials

G141-09(2021)

Standard Guide for Addressing Variability in Exposure Testing of Nonmetallic Materials

G147-17

Standard Practice for Conditioning and Handling of Nonmetallic Materials for Natural and Artificial Weathering Tests

D1293-18

Standard Test Methods for pH of Water

D3826-18

Standard Practice for Determining Degradation End Point in Degradable Polyethylene and Polypropylene Using a Tensile Test

D3593-80(1986)

Test Method for Molecular Weight Averages and Molecular Weight Distribution of Certain Polymers by Liquid Size-Exclusion Chromatography (Gel Permeation Chromatography GPC) Using Universal Calibration (Withdrawn 1993)

D2565-23

Standard Practice for Xenon-Arc Exposure of Plastics Intended for Outdoor Applications

DIN 53384

Testing of Plastics: Artificial Weathering or Exposure in Laboratory Exposure Weathering or Exposure in Laboratory Exposure Apparatus to UV Radiation

Publication C.I.E.

No. 85 (1989) Publication No. CIE 85, 1 st Ed., 1989 Technical Report, Solar Spectral Irradiance, available from U.S. National Committee CIE, Mr. Thomas M. Lemons, TLA-Lighting Consultants, Inc., 72 Loring Ave., Salem, MA 01970.

ISO 4892-2

Plastics--Method of Exposure to Laboratory Light Sources--Part 2, Xenon Arc Sources Available from American National Standards Institute (ANSI), 25 W. 43rd St., 4th Floor, New York, NY 10036.

G169-01(2021)

Standard Guide for Application of Basic Statistical Methods to Weathering Tests

D882-18

Standard Test Method for Tensile Properties of Thin Plastic Sheeting

D883-24

Standard Terminology Relating to Plastics

G155-21

Standard Practice for Operating Xenon Arc Lamp Apparatus for Exposure of Materials

G151-19

Standard Practice for Exposing Nonmetallic Materials in Accelerated Test Devices that Use Laboratory Light Sources

D5870-22

Standard Practice for Calculating Property Retention Index of Plastics

D3890-18

Standard Practice for Number of Strokes to Prime a Mechanical Pump Dispenser