ASTM D5116-97 - 10.12.1997
 
1. Scope

1.1 The use of small environmental test chambers to develop emission characteristics of indoor materials and products is still evolving. Modifications and variations in equipment, testing procedures, and data analysis are made as the work in the area progresses. Until the interested parties agree upon standard testing protocols, differences in approach will occur. This guide will provide assistance by describing equipment and techniques suitable for determining organic emissions from indoor materials. Specific examples are provided to illustrate existing approaches; these examples are not intended to inhibit alternative approaches or techniques that will produce equivalent or superior results.

1.2 Small chambers have obvious limitations. Normally, only samples of larger materials (for example, carpet) are tested. Small chambers are not applicable for testing complete assemblages (for example, furniture). Small chambers are also inappropriate for testing combustion devices (for example, kerosene heaters) or activities (for example, use of aerosol spray products). For some products, small chamber testing may provide only a portion of the emission profile of interest. For example, the rate of emissions from the application of high solvent materials (for example, paints and waxes) via brushing, spraying, rolling, etc. are generally higher than the rate during the drying process. Small chamber testing can not be used to evaluate the application phase of the coating process.

1.3 The guide does not provide specific guidance for determining emissions of formaldehyde from pressed wood products, since large chamber testing methods for such emissions are well developed and widely used. It is possible, however, that the guide could be used to support alternative testing methods.

1.4 While the ultimate purpose of any evaluation of indoor materials is to determine whether the emissions can contribute to health or comfort problems, this guide is only applicable to the determination of the emissions themselves. The effect of the emissions (for example, toxicity) is beyond the scope of the guide.

1.5 As an ASTM guide, options are described, but specific courses of action are not recommended. The purpose of this guide is to increase the awareness of the user to available techniques for evaluating organic emissions from indoor materials/products via small chamber testing and to provide information from which subsequent evaluation and standardization can be derived.

1.6 Within the context of the limitations discussed in this section, the purpose of this guide is to describe the methods and procedures for determining organic emission rates from indoor materials/products using small environmental test chambers. The techniques described are useful for both routine product testing by manufacturers and testing laboratories and for more rigorous evaluation by indoor air quality (IAQ) researchers. Appendix X1 provides additional references for readers wishing to supplement the information contained in this guide.

1.7 The values stated in SI units are to be regarded as standard.

1.8 This standard does not purport to address the safety problems associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

 
2. Referenced Documents

D6670-25

Standard Practice for Full-Scale Chamber Determination of Volatile Organic Emissions from Indoor Materials/Products

D6803-25

Standard Practice for Testing and Sampling of Volatile Organic Compounds (Including Carbonyl Compounds) Emitted from Architectural Coatings Using Small-Scale Environmental Chambers

D6485-18

Standard Guide for Risk Characterization of Acute and Irritant Effects of Short-Term Exposure to Volatile Organic Chemicals Emitted from Bedding Sets (Withdrawn 2024)

D6330-20

Standard Practice for Determination of Volatile Organic Compounds (Excluding Formaldehyde) Emissions from Wood-Based Panels Using Small Environmental Chambers Under Defined Test Conditions

D6196-23

Standard Practice for Choosing Sorbents, Sampling Parameters and Thermal Desorption Analytical Conditions for Monitoring Volatile Organic Chemicals in Air

D6177-19(2024)

Standard Practice for Determining Emission Profiles of Volatile Organic Chemicals Emitted from Bedding Sets

D3687-19

Standard Test Method for Analysis of Organic Compound Vapors Collected by the Activated Charcoal Tube Adsorption Method

D3686-20

Standard Practice for Sampling Atmospheres to Collect Organic Compound Vapors (Activated Charcoal Tube Adsorption Method)

D3609-22

Standard Practice for Calibration Techniques Using Permeation Tubes

D3195-90(1998)e1

Standard Practice for Rotameter Calibration

D7143-24

Standard Practice for Emission Cells for the Determination of Volatile Organic Emissions from Indoor Materials/Products

D1914-95(2022)

Standard Practice for Conversion Units and Factors Relating to Sampling and Analysis of Atmospheres

E355-96(2021)e1

Standard Practice for Gas Chromatography Terms and Relationships (Includes all amendments and changes 4/28/2021).

E1333-22

Standard Test Method for Determining Formaldehyde Concentrations in Air and Emission Rates from Wood Products Using a Large Chamber

D1356-20a

Standard Terminology Relating to Sampling and Analysis of Atmospheres (Includes all amendments and changes 9/7/2020).

D1193-24

Standard Specification for Reagent Water