ASTM D512-23 - 1.4.2023
 
Significance and Use

4.1?Chloride ion is under regulation in waste water, and must, therefore, be measured accurately. It is highly detrimental to high-pressure boiler systems and to stainless steel, so monitoring is essential for prevention of damage. Chloride analysis is widely used as a tool for estimating the cycles of concentration, such as in cooling tower applications. Processing waters and pickling solutions used in the food processing industries also require dependable methods of analysis for chloride.

 
1. Scope

1.1?These test methods cover the determination of chloride ion in water, wastewater (Test Method C only), and brines. The following three test methods are included:

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Sections

Test Method A (Mercurimetric Titration)

7 to14

Test Method B (Silver Nitrate Titration)

15 to 21

Test Method C (Ion-Selective Electrode Method)

22 to 29

1.2?Test Methods A, B, and C were validated under Practice D2777 77, and only Test Method B conforms also to Practice D2777 86. Refer to Sections 14, 21, and 29 for further information.

1.3?The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.

1.4?This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. For a specific hazard statement, see 26.1.1.

1.5?A former colorimetric test method was discontinued. Refer to Appendix X1 for historical information.

1.6?This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

 
2. Referenced Documents

D5810-96(2021)

Standard Guide for Spiking into Aqueous Samples

D5847-22

Standard Practice for Writing Quality Control Specifications for Standard Test Methods for Water Analysis

D1129-24

Standard Terminology Relating to Water

D1066-18(2025)

Standard Practice for Sampling Steam

E200-23

Standard Practice for Preparation, Standardization, and Storage of Standard and Reagent Solutions for Chemical Analysis

D1193-24

Standard Specification for Reagent Water

D2777-21

Standard Practice for Determination of Precision and Bias of Applicable Test Methods of Committee D19 on Water

D3370-25

Standard Practices for Sampling Water from Flowing Process Streams

D4127-18a

Standard Terminology Used with Ion-Selective Electrodes (Includes all amendments and changes 6/29/2018).