ASTM D5128-90(1999)e1 - 10.6.1999
 
1. Scope

1.1 This test method covers the precise on-line determination of pH in water samples of conductivity lower than 100 [mu]S/cm (see Tables 1 and 2) over the pH range of 3 to 11 (see Fig. 1), under field operating conditions, utilizing a sealed, non-refillable, reference electrode. pH measurements of water of low conductivity are problematical for conventional pH electrodes, methods, and related measurement apparatus.

1.2 This test method includes the procedures and equipment required for the continuous pH measurement of low conductivity water sample streams including the requirements for the control of sample stream pressure, flow rate, and temperature.

1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

 
2. Referenced Documents

D1193-24

Standard Specification for Reagent Water

D1129-24

Standard Terminology Relating to Water

D5464-25

Standard Test Method for pH Measurement of Water of Low Conductivity

D4453-17(2025)

Standard Practice for Handling of High Purity Water Samples

D3864-12(2021)

Standard Guide for On-Line Monitoring Systems for Water Analysis

D2777-21

Standard Practice for Determination of Precision and Bias of Applicable Test Methods of Committee D19 on Water

D1293-18

Standard Test Methods for pH of Water