ASTM D513-02 - 10.7.2002
 
1. Scope

1.1 These test methods provide for the measurement of total or dissolved carbon dioxide present as carbon dioxide (CO2), carbonic acid, bicarbonate ion, and carbonate ion in water:

RangeSections
Test Method A (Gas Sensing Electrode)2 to 800 mg/L8 to 15
Test Method B (CO2 Evolution, Coulometric Titration)5 to 800 mg/L16 to 24

1.2 Carbon dioxide may also be detected from carbonates present in particulates in samples.

1.3 Test Method A is applicable to various natural waters and brines.

1.4 Test Method B is applicable to natural waters, brines, and various industrial waters as delineated in .

1.5 It is the user's responsibility to ensure the validity of these test methods on waters of untested matrices.

1.6 Several test methods were discontinued from this standard in 1988. Refer to for historical information.

1.7 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

 
2. Referenced Documents

D1193-24

Standard Specification for Reagent Water

D1066-18(2025)

Standard Practice for Sampling Steam

D1129-24

Standard Terminology Relating to Water

D1293-18

Standard Test Methods for pH of Water

D2777-21

Standard Practice for Determination of Precision and Bias of Applicable Test Methods of Committee D19 on Water

D3370-25

Standard Practices for Sampling Water from Flowing Process Streams

D5847-22

Standard Practice for Writing Quality Control Specifications for Standard Test Methods for Water Analysis

E200-23

Standard Practice for Preparation, Standardization, and Storage of Standard and Reagent Solutions for Chemical Analysis