ASTM D5134-98(2008)e1 - 1.5.2008
 
Significance and Use

A knowledge of the hydrocarbon components comprising a petroleum naphtha, reformate, or alkylate is useful in valuation of crude oils, in alkylation and reforming process control, in product quality assessment, and for regulatory purposes. Detailed hydrocarbon composition is also used as input in the mathematical modeling of refinery processes.

Separation of naphtha components by the procedure described in this test method can result in some peaks that represent coeluting compounds. This test method cannot attribute relative concentrations to the coelutants. In the absence of supporting information, use of the results of this test method for purposes which require such attribution is not recommended.

 
1. Scope

1.1 This test method covers the determination of hydrocarbon components of petroleum naphthas as enumerated in Table 1. Components eluting after n-nonane (bp 150.8°C) are determined as a single group.

1.2 This test method is applicable to olefin-free (<2 % olefins by liquid volume) liquid hydrocarbon mixtures including virgin naphthas, reformates, and alkylates. Olefin content can be determined by Test Method D 1319. The hydrocarbon mixture must have a 98 % point of 250°C or less as determined by Test Method D 3710.

1.3 Components that are present at the 0.05 mass % level or greater can be determined.

1.4 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.

1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. Specific warning statements are given in Section 7.

 
2. Referenced Documents

D3700-26

Standard Practice for Obtaining LPG Samples Using a Floating Piston Cylinder

D3710-95(1999)e1

Standard Test Method for Boiling Range Distribution of Gasoline and Gasoline Fractions by Gas Chromatography

D4057-22

Standard Practice for Manual Sampling of Petroleum and Petroleum Products

D5443-23

Standard Test Method for Paraffin, Naphthene, and Aromatic Hydrocarbon Type Analysis in Petroleum Distillates Through 200 ?C by Multi-Dimensional Gas Chromatography

D1319-26

Standard Test Method for Hydrocarbon Types in Liquid Petroleum Products by Fluorescent Indicator Adsorption

D6839-25

Standard Test Method for Hydrocarbon Types, Oxygenated Compounds, Benzene, and Toluene in Spark Ignition Engine Fuels by Multidimensional Gas Chromatography

D6729-25

Standard Test Method for Determination of Individual Components in Spark Ignition Engine Fuels by 100 Metre Capillary High Resolution Gas Chromatography

D6730-26

Standard Test Method for Determination of Individual Components in Spark Ignition Engine Fuels by 100-Metre Capillary (with Precolumn) High-Resolution Gas Chromatography

D6733-24

Standard Test Method for Determination of Individual Components in Spark Ignition Engine Fuels by 50-Metre Capillary High Resolution Gas Chromatography

D7096-25

Standard Test Method for Determination of the Boiling Range Distribution of Gasoline by Wide-Bore Capillary Gas Chromatography