ASTM D5156-22 - 1.9.2022
 
Significance and Use

5.1?Standards for O3 in the atmosphere have been promulgated by government authorities to protect the health and welfare of the public (6) and also for the protection of industrial workers (7).

5.2?Although O3 itself is a toxic material, in ambient air it is primarily the photochemical oxidants formed along with O3 in polluted air exposed to sunlight that cause smog symptoms such as lachrymation and burning eyes. Ozone is much more easily monitored than these photochemical oxidants and provides a good indication of their concentrations, and it is therefore the substance that is specified in air quality standards and regulations.

 
1. Scope

1.1?This test method describes the sampling and continuous analysis of ozone (O3) in the atmosphere at concentrations ranging from 10 to 2000 ?g/m3 of O3 in air (5 ppb(v) to 1 ppm(v)).

1.1.1?The test method is limited to applications by its sensitivity to interferences as described in Section 6. The interference sensitivities may limit its use for ambient and workplace atmospheres.

1.2?The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.

1.3?This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.

1.4?This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

 
2. Referenced Documents

D3249-95(2019)

Standard Practice for General Ambient Air Analyzer Procedures

D1914-95(2022)

Standard Practice for Conversion Units and Factors Relating to Sampling and Analysis of Atmospheres

D1357-26

Standard Practice for Planning the Sampling of the Ambient Atmosphere

D1356-20a

Standard Terminology Relating to Sampling and Analysis of Atmospheres (Includes all amendments and changes 9/7/2020).

D3631-25

Standard Test Methods for Measuring Surface Atmospheric Pressure

Quality Assurance Handbook for Air Pollution Measurement Systems, Vol II, Ambient Air Specific Methods

EPA-600/4-76-005

Quality Assurance Handbook for Air Pollution Measurement Systems, Vol I, Principles Available from National Technical Information Service (NTIS), 5301 Shawnee Rd., Alexandria, VA 22312, http://www.ntis.gov.

IEEE/ASTM SI-10

Practice for Use of the International System of Units (SI) (the Modernized Metric System)

D5110-22a

Standard Practice for Calibration of Ozone Monitors and Certification of Ozone Transfer Standards Using Ultraviolet Photometry (Includes all amendments and changes 10/22/2024).

D5011-17(2026)

Standard Practices for Calibration of Ozone Monitors Using Transfer Standards

D3670-91(2022)

Standard Guide for Determination of Precision and Bias of Methods of Committee D22