ASTM D5194-11 - 1.2.2011
 
Significance and Use

Organic and inorganic chlorine compounds can have a deleterious effect on equipment and reactions in processes involving aromatic hydrocarbons.

Maximum chloride levels are often specified for process streams and for aromatic hydrocarbon products.

 
1. Scope

1.1 This test method covers the determination of total chloride (organic and inorganic) in liquid aromatic hydrocarbons and cyclohexane.

1.2 The test method is applicable to samples with chloride concentrations of 1 to 25 mg/kg.

1.3 Bromides and iodides, if present, will be calculated as chlorides.

1.4 Materials, such as styrene, that are polymerized by sodium biphenyl reagent cannot be analyzed by this test method.

1.5 In determining the conformance of the test results using this method to applicable specifications, results shall be rounded off in accordance with the rounding-off method of Practice E29.

1.6 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.

1.7 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. For a specific hazard statement, see Section 7.

 
2. Referenced Documents

D891-25

Standard Test Methods for Specific Gravity, Apparent, of Liquid Industrial Chemicals

D3437-15(2022)

Standard Practice for Sampling and Handling Liquid Cyclic Products

D1193-24

Standard Specification for Reagent Water

D1555M-22

Standard Test Method for Calculation of Volume and Weight of Industrial Aromatic Hydrocarbons and Cyclohexane [Metric]

E29-22

Standard Practice for Using Significant Digits in Test Data to Determine Conformance with Specifications

OSHA Regulations, 29 CFR

paragraphs 1910.1000 and 1910.1200

D3505-18

Standard Test Method for Density or Relative Density of Pure Liquid Chemicals (Withdrawn 2023)

D4052-22

Standard Test Method for Density, Relative Density, and API Gravity of Liquids by Digital Density Meter

D6809-24

Standard Guide for Quality Control and Quality Assurance Procedures for Aromatic Hydrocarbons and Related Materials