ASTM D5315-04(2011) - 1.5.2011
 
Significance and Use

N-methylcarbamates and n-methylcarbomoyloximes are used in agriculture as insecticides and herbicides. They are sometimes found in both surface and ground waters and can be toxic to animals and plants at moderate to high concentrations. The manufacturing precursors and degradation products may be equally as hazardous to the environment.

 
1. Scope

1.1 This is a high-performance liquid chromatographic (HPLC) test method applicable to the determination of certain n-methylcarbamoyloximes and n-methylcarbamates in ground water and finished drinking water (1) . This test method is applicable to any carbamate analyte that can be hydrolyzed to a primary amine. The following compounds have been validated using this test method:

 
2. Referenced Documents

EPA Method 531.2,

Revision 1.0, USEPA, EMSL-Cincinnati, 2001 Published by the U.S. Environmental Protection Agency, Environmental Monitoring and Support Laboratory, Cincinnati, OH 45268, 2001.

D1129-24

Standard Terminology Relating to Water

D1192-98

Standard Guide for Equipment for Sampling Water and Steam in Closed Conduits (Withdrawn 2003)

D1193-24

Standard Specification for Reagent Water

D2777-21

Standard Practice for Determination of Precision and Bias of Applicable Test Methods of Committee D19 on Water

D3370-25

Standard Practices for Sampling Water from Flowing Process Streams

D3694-96(2024)

Standard Practices for Preparation of Sample Containers and for Preservation of Organic Constituents

E682-92(2026)

Standard Practice for Liquid Chromatography Terms and Relationships