ASTM D5373-93(1997) - 1.1.1993
 
1. Scope

1.1 These test methods cover the instrumental determination of carbon, hydrogen, and nitrogen in laboratory samples of coal and coke prepared in accordance with Test Methods D2013 and D346.

1.2 Within the limitations outlined below, these test methods are applicable to either the air-dry or moisture-free laboratory sample, or both.

1.2.1 For instrumental systems in which the moisture and waters of hydration in the sample are liberated with (and only with) the oxidation products upon combustion, the analyses can be performed on a test specimen of the air-dry sample (Note 1). Concentrations determined on this air-dried basis represent the total carbon (including that present as carbonate), total hydrogen (including that present as water), and total nitrogen.

Note 1-These systems are also satisfactory for determining the subject materials in the moisture-free sample.

1.2.2 For systems in which the moisture and hydrates are otherwise liberated, the analysis shall be performed on the moisture-free sample. Values obtained on this basis represent the total carbon, organic hydrogen, and total nitrogen.

1.3 These test methods can be used to provide for the requirements specified in Practice D3176 for the ultimate analysis.

1.4 The values stated in SI units shall be regarded as the standard.

1.5 This standard does not purport to address all of the safety problems, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. Specific precautionary statements are given in 8.3.1.

 
2. Referenced Documents

D121-24

Standard Terminology of Coal and Coke

D3173-11

Standard Test Method for Moisture in the Analysis Sample of Coal and Coke

D3180-25

Standard Practice for Calculating Coal and Coke Analyses from As-Determined to Different Bases

D3176-24

Standard Practice for Ultimate Analysis of Coal and Coke

D346-D346M-11

Standard Practice for Collection and Preparation of Coke Samples for Laboratory Analysis

D2013-07

Standard Practice for Preparing Coal Samples for Analysis

ISO 5725-6

Accuracy (Trueness and Precision) of Measurement Methods and Results Part 6: Use in Practice of Accuracy Values Available from American National Standards Institute (ANSI), 25 W. 43rd St., 4th Floor, New York, NY 10036, http://www.ansi.org.

D7582-24

Standard Test Methods for Proximate Analysis of Coal and Coke by Macro Thermogravimetric Analysis

D5865-13

Standard Test Method for Gross Calorific Value of Coal and Coke