ASTM D5542-94(1999)e1 - 10.6.1999
 
1. Scope

1.1 These test methods cover the determination of trace ([mu]g/L) levels of fluoride, acetate, formate, chloride, phosphate, and sulfate in high purity water using ion chromatography in combination with sample preconcentration. Other anions, such as bromide, nitrite, nitrate, sulfite, and iodide can be determined by this method. However, since they are rarely present in significant concentrations in high purity water, they are not included in this test method. Two test methods are presented and their ranges of application, as determined by a collaborative study, are as follows:

1.2 It is the user's responsibility to ensure the validity of these test methods for waters of untested matrices.

1.3 The common practical range of Test Method A is as follows: chloride, 1 to 100 [mu]g/L, phosphate, 3 to 100 [mu]g/L, and sulfate, 2 to 100 [mu]g/L.

1.4 The common practical range of Test Method B is as follows: fluoride, 1 to 100 [mu]g/L, acetate, 10 to 200 [mu]g/L, and formate, 5 to 200 [mu]g/L.

1.5 The values stated in SI units are to be regarded as the standard.

1.6 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

 
2. Referenced Documents

D3370-25

Standard Practices for Sampling Water from Flowing Process Streams

D1192-98

Standard Guide for Equipment for Sampling Water and Steam in Closed Conduits (Withdrawn 2003)

D1129-24

Standard Terminology Relating to Water

D5847-22

Standard Practice for Writing Quality Control Specifications for Standard Test Methods for Water Analysis

D1066-18(2025)

Standard Practice for Sampling Steam

D1193-24

Standard Specification for Reagent Water

D3856-11

Standard Guide for Management Systems in Laboratories Engaged in Analysis of Water

D4210-89(1996)e1

Standard Practice for Intralaboratory Quality Control Procedures and a Discussion on Reporting Low-Level Data (Withdrawn 2002)

D5810-96(2026)

Standard Guide for Spiking into Aqueous Samples

D4453-17(2025)

Standard Practice for Handling of High Purity Water Samples