ASTM D5666-95(2014) - 1.8.2014
 
Significance and Use

5.1 This test method is designed to determine the purity of p-phenylenediamine antidegradants.

5.2 Since the results of this test method are based on an integrated peak area as determined by HPLC, it is assumed that all analytes of interest are resolved from interfering peaks.

 
1. Scope

1.1 This test method covers the purity of Type I, II, and III p-phenylenediamine (PPD) antidegradants as described in Classification D4676 by high performance liquid chromatography (HPLC) using ultraviolet detection and external standard calculations.

1.2 Expertise in HPLC is necessary to the successful application of this test method.

1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.

1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

 
2. Referenced Documents

ISO?5725

Precision of Test Methods

ISO?6472

Rubber Compounding Ingredients--Abbreviations

D4676-94(2025)

Standard Classification for Rubber Compounding Materials—Antidegradants

D4483-25

Standard Practice for Evaluating Precision for Test Method Standards in the Rubber and Carbon Black Manufacturing Industries

D3853-22

Standard Terminology Relating to Rubber and Rubber Latices—Abbreviations for Chemicals Used in Compounding