ASTM D5769-98 - 10.7.1998
 
1. Scope

1.1 This test method covers the determination of benzene, toluene, and total aromatics in finished motor gasoline, including reformulated gasoline (RFG) containing oxygenated blending components, by gas chromatography/mass spectrometry (GC/MS).

1.2 This test method is applicable to the following concentration ranges, in liquid volume %, for the following aromatics: benzene, 0.1 to 3%; toluene, 1 to 15%; and total (C6-C12) aromatics, 10 to 40%. The test method has not been tested by ASTM for gasoline samples containing a concentration of uncalibrated C10-C12 aromatic compounds greater than approximately 3 volume %. Also, the test method has not been tested by ASTM for individual hydrocarbon process streams in a refinery, such as reformates, fluid catalytic cracked naphthas, etc., used in blending of gasolines.

1.3 Results are reported to the nearest 0.01% for benzene and 0.1% for the other aromatics by either mass or liquid volume.

1.4 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.

1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

 
2. Referenced Documents

D1298-24

Standard Test Method for Density, Relative Density, or API Gravity of Crude Petroleum and Liquid Petroleum Products by Hydrometer Method

D4307-17(2021)

Standard Practice for Preparation of Liquid Blends for Use as Analytical Standards

D4052-22

Standard Test Method for Density, Relative Density, and API Gravity of Liquids by Digital Density Meter

D6708-24

Standard Practice for Statistical Assessment and Improvement of Expected Agreement Between Two Test Methods that Purport to Measure the Same Property of a Material

D3606-26

Standard Test Method for Determination of Benzene and Toluene in Spark Ignition Fuels by Gas Chromatography

D4057-22

Standard Practice for Manual Sampling of Petroleum and Petroleum Products