ASTM D6047-99(2003) - 1.11.2003
 
1. Scope

1.1 These test methods cover the determination of the content of 5-ethylidenenorbornene (ENB) or Dicyclopentadiene (DCPD) in ethylene-propylene-diene (EPDM) terpolymers. They are applicable to diene contents in the 0.1 to 10 mass % range.

1.2 ENB and DCPD are dienes introduced in ethylene/propylene rubbers to generate specific cure properties. Since high precision for diene content determination has become very important, a Fourier Transform Infrared Spectroscopic (FTIR) method was developed. Diene determination was performed in the past by a refractive index technique.

Note 1—The procedures for % ENB and % DCPD differ only in the location in the infrared (IR) of the IR peak being quantified.

1.3 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.

1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

 
2. Referenced Documents

E168-16(2023)

Standard Practices for General Techniques of Infrared Quantitative Analysis

D4483-25

Standard Practice for Evaluating Precision for Test Method Standards in the Rubber and Carbon Black Manufacturing Industries

D297-21(2026)

Standard Test Methods for Rubber Products—Chemical Analysis

D1416-89

Test Methods for Rubber from Synthetic Sources--Chemical Analysis (Withdrawn 1996)

D3900-17(2025)

Standard Test Methods for Rubber—Determination of Ethylene Units in Ethylene-Propylene Copolymers (EPM) and in Ethylene-Propylene-Diene Terpolymers (EPDM) by Infrared Spectrometry

D3568-03(2022)

Standard Test Methods for Rubber—Evaluation of EPDM (Ethylene Propylene Diene Terpolymers) Including Mixtures With Oil

E932-89(2021)

Standard Practice for Describing and Measuring Performance of Dispersive Infrared Spectrometers

E1421-99(2021)

Standard Practice for Describing and Measuring Performance of Fourier Transform Mid-Infrared (FT-MIR) Spectrometers: Level Zero and Level One Tests

Specification

for Evaluation of Research Quality Analysis of Infrared Spectra