ASTM D6301-03 - 10.8.2003
 
Significance and Use

The transport of any filterable matter or corrosion products from the preboiler cycle has been shown to be detrimental to all types of steam generating equipment. Corrosion product transport as low as 10 ppb can have significant impact on steam generators performance.

Deposited corrosion products on PWR steam generator tubes can reduce heat transfer, and, if the deposit is sufficiently thick, can provide a local area for impurities in the bulk water to concentrate, resulting in a corrosive environment. In BWR plants, the transport of corrosion products can cause fuel failure, out of core radiation problems from activation reactions, and other material related problems.

In fossil plants, the transport of corrosion products can reduce heat transfer in the boilers leading to tube failures from overheating. The removal of these corrosion products by chemical cleaning is expensive and potentially harmful to the boiler tubes.

Normally, grab samples are not sensitive enough to detect changes in the level of corrosion product transport. Also, system transients may be missed by only taking grab samples. An integrated sample over time will increase the sensitivity for detecting the corrosion products and provide a better understanding of the total corrosion product transport to steam generators.

 
1. Scope

1.1 This practice is applicable for sampling condensed steam or water, such as boiler feedwater, for the collection of filterable and (optional) nonfilterable matter using 0.45-m membrane filter (filterable matter) and ion exchange media (nonfilterable matter). As the major filterable containment found in most boiler feedwaters is some form of corrosion product from the preboiler system, the device used for this practice is commonly called a corrosion product sampler.

1.2 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

 
2. Referenced Documents

D1971-16(2021)e1

Standard Practices for Digestion of Water Samples for Determination of Metals by Flame Atomic Absorption, Graphite Furnace Atomic Absorption, Plasma Emission Spectroscopy, or Plasma Mass Spectrometry (Includes all amendments and changes 12/22/2021).

D3864-12(2021)

Standard Guide for On-Line Monitoring Systems for Water Analysis

D3370-25

Standard Practices for Sampling Water from Flowing Process Streams

D2332-13(2021)

Standard Practice for Analysis of Water-Formed Deposits by Wavelength-Dispersive X-Ray Fluorescence

D2777-21

Standard Practice for Determination of Precision and Bias of Applicable Test Methods of Committee D19 on Water

D1193-24

Standard Specification for Reagent Water

D1129-24

Standard Terminology Relating to Water

D1066-18(2025)

Standard Practice for Sampling Steam