ASTM D6348-03(2010) - 1.10.2010
 
Significance and Use

The FTIR measurements provide for multicomponent on-site analysis of source effluent.

This test method provides the volume concentration of detected analytes. Converting the volume concentration to a mass emission rate using a particular compound's molecular weight, and the effluent volumetric flow rate, temperature and pressure is useful for determining the impact of that compound to the atmosphere.

Known concentrations of target analytes are spiked into the effluent to evaluate the sampling and analytical system's effectiveness for transport and quantification of the target analytes, and to ensure that the data collected are meaningful.

The FTIR measurement data are used to evaluate process conditions, emissions control devices, and for determining compliance with emission standards or other applicable permits.

Data quality objectives for each specific testing program must be specified and outlined in a test plan (Annex A1). Supporting data are available from ASTM Headquarters Request RR:D22-1027.

 
1. Scope

1.1 This field test method employs an extractive sampling system to direct stationary source effluent to an FTIR spectrometer for the identification and quantification of gaseous compounds. This test method is potentially applicable for the determination of compounds that (1) have sufficient vapor pressure to be transported to the FTIR spectrometer and (2) absorb a sufficient amount of infrared radiation to be detected.

1.2 This field test method provides near real time analysis of extracted gas samples from stationary sources. Gas streams with high moisture content may require conditioning to minimize the excessive spectral absorption features imposed by water vapor.

 
2. Referenced Documents

D1356-20a

Standard Terminology Relating to Sampling and Analysis of Atmospheres (Includes all amendments and changes 9/7/2020).

Method 4 Series

Determination of Moisture Content in Stack Gases

Method 3 Series

Gas Analysis for Carbon Dioxide, Oxygen, Excess Air, and Dry Molecular Weight

Method 2 Series

Determination of Stack Gas Velocity and Volumetric Flow Rate (Type S Pitot Tube)

Method 1

Sample and Velocity Traverses for Stationary Sources

E1252-98(2021)

Standard Practice for General Techniques for Obtaining Infrared Spectra for Qualitative Analysis

D3195-90(1998)e1

Standard Practice for Rotameter Calibration

E168-16(2023)

Standard Practices for General Techniques of Infrared Quantitative Analysis