ASTM D6349-21 - 1.9.2021
 
Significance and Use

5.1?A compositional analysis of coal and coke and their associated combustion residues are often useful in assessing their quality. Knowledge of the elemental composition of the associated residues is also useful in predicting the elemental enrichment/depletion compositional behavior of ashes and slags in comparison to the mass fraction in the parent coal. Utilization of the ash by-products and hazardous potential may also depend on the chemical composition and leachability of the inorganic constituents of the coal ash.

5.2?The chemical composition of laboratory-prepared ash may not exactly represent the composition of mineral matter in coal or the composition of fly ash and slag resulting from commerical-scale burning of the coal.

 
1. Scope

1.1?This test method covers a procedure for the analysis of the commonly determined major and minor elements in coal, coke, and solid residues from combustion of coal and coke. These residues may be laboratory ash, bottom ash, fly ash, flue gas desulfurization sludge, and other combustion process residues.

Note 1:?There are two interlaboratory studies associated with this test method. The first was conducted in 1997 ( RR:D05-1035)2 and the second was conducted in 2007 ( RR:D05-1032).3 Sulfur trioxide was only included in the 2007 study, and that study only included combustion residues derived from ash and no combustion residues derived from coke.

1.2?UnitsThe values stated in SI units are to be regarded as standard. The values given in parentheses after SI units are provided for information only and are not considered standard.

1.3?This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.

1.4?This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

 
2. Referenced Documents

D121-24

Standard Terminology of Coal and Coke

D346-25

Standard Practice for Collection and Preparation of Coke Samples for Laboratory Analysis

D1193-24

Standard Specification for Reagent Water

D3173-11

Standard Test Method for Moisture in the Analysis Sample of Coal and Coke

D3174-12(2018)e1

Standard Test Method for Ash in the Analysis Sample of Coal and Coke from Coal (Includes all amendments and changes 9/17/2020).

D2013-07

Standard Practice for Preparing Coal Samples for Analysis

D7348-21

Standard Test Methods for Loss on Ignition (LOI) of Solid Combustion Residues

D7582-24

Standard Test Methods for Proximate Analysis of Coal and Coke by Macro Thermogravimetric Analysis

E691-23

Standard Practice for Conducting an Interlaboratory Study to Determine the Precision of a Test Method

ISO/IEC Guide 99:2007

International vocabulary of metrology -- Basic and general concepts and associated terms (VIM)

D3180-25

Standard Practice for Calculating Coal and Coke Analyses from As-Determined to Different Bases