ASTM D6357-21b - 1.12.2021
 
Significance and Use

5.1?Coal contains several elements whose individual mass fractions are generally less than 0.01 %. These elements are commonly and collectively referred to as trace elements. These elements primarily occur as part of the mineral matter in coal. The potential release of certain trace elements from coal combustion sources has become an environmental concern.

5.2?The ash prepared in accordance with these provisional test methods quantitatively retains the elements listed in 1.1 and is representative of their mass fractions in the coal or coke.

 
1. Scope

1.1?These test methods pertain to the determination of antimony, arsenic, beryllium, cadmium, chromium, cobalt, copper, lead, manganese, molybdenum, nickel, vanadium, and zinc in coal and coke. These test methods can also be used for the analysis of residues from coal combustion processes. Additionally, there are specific test methods outlined that pertain to the determination of rare earth elements in coal and coal combustion residues.

Note 1:?These test methods may be applicable to the determination of other trace elements.

Note 2:?Rare earth elements are understood to include: cerium, dysprosium, erbium, europium, gadolinium, holmium, lanthanum, lutetium, neodymium, praseodymium, samarium, scandium, terbium, thulium, ytterbium, and yttrium.

1.2?UnitsThe values stated in SI units are to be regarded as standard. The values given in parentheses after SI units are provided for information only and are not considered standard.

1.2.1?All percentages are percent mass fractions unless otherwise noted.

1.3?This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.

1.4?This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

 
2. Referenced Documents

D121-24

Standard Terminology of Coal and Coke

EPA/600/4-91/010

Methods for the Determination of Metals in Environmental Samples Available from Superintendent of Documents, U.S. Printing Office, Washington, DC 20402.

E691-23

Standard Practice for Conducting an Interlaboratory Study to Determine the Precision of a Test Method

D7582-24

Standard Test Methods for Proximate Analysis of Coal and Coke by Macro Thermogravimetric Analysis

D346-25

Standard Practice for Collection and Preparation of Coke Samples for Laboratory Analysis

D7448-16

Standard Practice for Establishing the Competence of Laboratories Using ASTM Procedures in the Sampling and Analysis of Coal and Coke (Withdrawn 2024)

D3180-25

Standard Practice for Calculating Coal and Coke Analyses from As-Determined to Different Bases

D3173-11

Standard Test Method for Moisture in the Analysis Sample of Coal and Coke

D2013-07

Standard Practice for Preparing Coal Samples for Analysis

D1193-24

Standard Specification for Reagent Water