ASTM D6468-22 - 1.5.2022
 
Significance and Use

5.1?This test method provides an indication of thermal oxidative stability of distillate fuels when heated to high temperatures that simulate those that may occur in some types of recirculating engine or burner fuel delivery systems. Results have not been substantially correlated to engine or burner operation. The test method can be useful for investigation of operational problems related to fuel thermal stability.

5.2?When the test method is used to monitor manufacture or storage of fuels, changes in filter rating values can indicate a relative change in inherent stability. Storage stability predictions are more reliable when correlated to longer-term storage tests, for example, Test Method D4625, or other lower temperature, long-term tests. When fuel samples are freshly produced, aging for 180 min, instead of the traditional 90 min interval, tends to give a result correlating more satisfactorily with the above methods (see Appendix X2).

5.3?The test method uses a filter paper with a nominal porosity of 11 ?m, which will not capture all of the sediment formed during aging but allows differentiation over a broad range. Reflectance ratings are also affected by the color of filterable insolubles, which may not correlate to the mass of the material filtered from the aged fuel sample. Therefore, no quantitative relationship exists between the pad rating and the gravimetric mass of filterable insolubles.

 
1. Scope

1.1?This test method covers relative stability of middle distillate fuels under high temperature aging conditions with limited air exposure. This test method is suitable for all No. 1 and No. 2 grades in Specifications D396, D975, D2880, and D3699. It is also suitable for similar fuels meeting other specifications.

1.2?This test method is not suitable for fuels whose flash point, as determined by Test Methods D56, D93, or D3828, is less than 38 ?C. This test method is not suitable for fuels containing residual oil.

1.3?The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.

1.3.1?ExceptionThe maximum vacuum includes inch-pound units in 6.5 and 11.2.

1.4?This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.

1.5?This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

 
2. Referenced Documents

D3699-25

Standard Specification for Kerosine

D2274-14(2019)

Standard Test Method for Oxidation Stability of Distillate Fuel Oil (Accelerated Method)

D56-22

Standard Test Method for Flash Point by Tag Closed Cup Tester

D93-26

Standard Test Methods for Flash Point by Pensky-Martens Closed Cup Tester

D396-26a

Standard Specification for Fuel Oils (Includes all amendments and changes 4/14/2026).

D975-26b

Standard Specification for Diesel Fuel (Includes all amendments and changes 3/31/2026).

D1500-24

Standard Test Method for ASTM Color of Petroleum Products (ASTM Color Scale)

D3828-16a(2021)

Standard Test Methods for Flash Point by Small Scale Closed Cup Tester (Includes all amendments and changes 7/26/2021).

D4057-22

Standard Practice for Manual Sampling of Petroleum and Petroleum Products

D4625-21

Standard Test Method for Middle Distillate Fuel Storage Stability at 43 ?C (110 ?F)

D5452-23

Standard Test Method for Particulate Contamination in Aviation Fuels by Laboratory Filtration

D2880-23

Standard Specification for Gas Turbine Fuel Oils