ASTM D6502-99(2003) - 10.12.1999
 
1. Scope

1.1 This test method covers the operation, calibration, and data interpretation for an on-line corrosion product (metals) monitoring system. The monitoring system is based on x-ray fluorescence (XRF) analysis of metals contained on membrane filters (for particulate forms) or resin membranes (for dissolved forms). Since the XRF detector is sensitive to a range of emission energy, this test method is applicable to simultaneous monitoring of the concentration levels of several metals including titanium, vanadium, chromium, manganese, iron, cobalt, nickel, copper, zinc, mercury, lead, and others in a flowing sample. A detection limit below 1 ppb can be achieved for most metals.

1.2 This test method includes a description of the equipment comprising the on-line metals monitoring system, as well as, operational procedures and system specifications.

This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

 
2. Referenced Documents

D3864-12(2021)

Standard Guide for On-Line Monitoring Systems for Water Analysis

D1129-24

Standard Terminology Relating to Water

D1066-18(2025)

Standard Practice for Sampling Steam

D5540-13(2021)

Standard Practice for Flow Control and Temperature Control for On-Line Water Sampling and Analysis

D2777-21

Standard Practice for Determination of Precision and Bias of Applicable Test Methods of Committee D19 on Water

D3370-25

Standard Practices for Sampling Water from Flowing Process Streams

D6301-21

Standard Practice for Collection of On-Line Composite Samples of Suspended Solids and Ionic Solids in Process Water

D4453-17(2025)

Standard Practice for Handling of High Purity Water Samples