ASTM D6581-00 - 10.7.2000
 
1. Scope

1.1 This test method covers the determination of the oxyhalides - chlorite, bromate, and chlorate, and bromide, in raw water, finished drinking water and bottled (non-carbonated) water by chemically suppressed ion chromatography. The ranges tested using this method for each analyte were as follows:

Chlorite20 to 500 g/L
Bromate5 to 30 g/L
Bromide20 to 200 g/L
Chlorate20 to 500 g/L

The upper limits may be extended by appropriate sample dilution or by the use of a smaller injection volume. Other ions of interest, such as fluoride, chloride, nitrite, nitrate, phosphate, and sulfate may also be determined using this method. However, analysis of these ions is not the object of this test method.

1.2 It is the user's responsibility to ensure the validity of these test methods for waters of untested matrices.

1.3 This test method is technically equivalent with Part B of U.S. EPA Method 300.1, titled "The Determination of Inorganic Anions in Drinking Water by Ion Chromatography".

1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

 
2. Referenced Documents

D5810-96(2026)

Standard Guide for Spiking into Aqueous Samples

D3370-25

Standard Practices for Sampling Water from Flowing Process Streams

D2777-21

Standard Practice for Determination of Precision and Bias of Applicable Test Methods of Committee D19 on Water

D1193-24

Standard Specification for Reagent Water

D5847-22

Standard Practice for Writing Quality Control Specifications for Standard Test Methods for Water Analysis

D1129-24

Standard Terminology Relating to Water

D3856-11

Standard Guide for Management Systems in Laboratories Engaged in Analysis of Water