ASTM D6888-03 - 10.3.2003
 
1. Scope

1.1 This method is used to determine the concentration of available inorganic cyanide in an aqueous wastewater or effluent. The method detects the cyanides that are free (HCN and CN-) and metal-cyanide complexes that are easily dissociated into free cyanide ions. The method does not detect the less toxic strong metal-cyanide complexes, cyanides that are not "amenable to chlorination."

1.2 This procedure is applicable over a range of approximately 2 to 400 μg/L (parts per billion) available cyanide. Higher concentrations can be analyzed by dilution or lower injection volume.

This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. Specific hazard statements are given in Note 2 and Section 8.

 
2. Referenced Documents

D2036-09(2022)

Standard Test Methods for Cyanides in Water

D1193-24

Standard Specification for Reagent Water

D1129-24

Standard Terminology Relating to Water

D7365-09a(2022)

Standard Practice for Sampling, Preservation and Mitigating Interferences in Water Samples for Analysis of Cyanide (Includes all amendments and changes 5/13/2022).

D5847-22

Standard Practice for Writing Quality Control Specifications for Standard Test Methods for Water Analysis

D6696-16(2023)

Standard Guide for Understanding Cyanide Species

D3856-11

Standard Guide for Management Systems in Laboratories Engaged in Analysis of Water