ASTM D7083-16(2022) - 1.7.2022
 
Significance and Use

5.1?Separation and identification of plasticizer components in PVC is necessary to correlate performance properties with polymer composition. This test method provides a means of determining monomeric plasticizers including adipates, azelates, benzoates, citrates, phthalates, sebacates, and trimellitates.

5.2?Other methods successfully used to analyze plasticizers are column chromatography, HPLC, GPC, FTIR, and GC/MS.

5.3?This method is not applicable to plasticizers with molecular weights over 700 g/mol including epoxidized soybean oil and polymeric plasticizers.

 
1. Scope

1.1?This practice provides for the separation and identification of monomeric plasticizers in poly (vinyl chloride) (PVC) compounds by gas chromatography (GC).

1.2?The text of this practice references notes and footnotes which provide explanatory material. These notes and footnotes (excluding those in Tables and Figures) shall not be considered as requirements of this standard.

1.3?Test Method D2124 is an alternative infrared procedure.

1.4?The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.

1.5?This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.

Note 1:?There is no known ISO equivalent to this standard.

1.6?This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

 
2. Referenced Documents

D3465-21

Standard Guide for Purity of Monomeric Plasticizers by Gas Chromatography

D2124-99e1

Standard Test Method for Analysis of Components in Poly(Vinyl Chloride) Compounds Using an Infrared Spectrophotometric Technique

D1600-18

Standard Terminology for Abbreviated Terms Relating to Plastics (Withdrawn 2024)

D883-26

Standard Terminology Relating to Plastics

E355-96(2021)e1

Standard Practice for Gas Chromatography Terms and Relationships (Includes all amendments and changes 4/28/2021).

IEEE/ASTM SI-10

Practice for Use of the International System of Units (SI), the Modernized Metric System

D7823-20

Standard Test Method for Determination of Low Level Phthalates in Poly (Vinyl Chloride) Plastics by Thermal Desorption“Gas Chromatography/Mass Spectrometry

E594-96(2026)

Standard Practice for Testing Flame Ionization Detectors Used in Gas or Supercritical Fluid Chromatography