ASTM D7096-16 - 1.1.2016
 
Significance and Use

5.1 The determination of the boiling range distribution of gasoline by gas chromatographic simulated distillation provides an insight into the composition of the components from which the gasoline has been blended. Knowledge of the boiling range distribution of gasoline blending components is useful for the control of refinery processes and for the blending of finished gasoline.

5.2 The determination of the boiling range distribution of light hydrocarbon mixtures by gas chromatographic simulated distillation has better precision than the conventional distillation by Test Method D86. Additionally, this test method provides more accurate and detailed information about the composition of the light ends. The distillation data produced by this test method are similar to that which would be obtained from a cryogenic, true boiling point (15 theoretical plates) distillation.

 
1. Scope

1.1 This test method covers the determination of the boiling range distribution of gasoline and liquid gasoline blending components. It is applicable to petroleum products and fractions with a final boiling point of 280 °C (536 °F) or lower, as measured by this test method.

1.2 This test method is designed to measure the entire boiling range of gasoline and gasoline components with either high or low vapor pressure and is commonly referred to as Simulated Distillation (SimDis) by gas chromatographers.

1.3 This test method has been validated for gasoline containing ethanol. Gasolines containing other oxygenates are not specifically excluded, but they were not used in the development of this test method.

1.4 This test method can estimate the concentration of n-pentane and lighter saturated hydrocarbons in gasoline.

1.5 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.

1.5.1 Results in degrees Fahrenheit can be obtained by simply substituting Fahrenheit boiling points in the calculation of the boiling point-retention time correlation.

1.6 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

 
2. Referenced Documents

E1510-95(2021)

Standard Practice for Installing Fused Silica Open Tubular Capillary Columns in Gas Chromatographs

E594-96(2026)

Standard Practice for Testing Flame Ionization Detectors Used in Gas or Supercritical Fluid Chromatography

D4814-25a

Standard Specification for Automotive Spark-Ignition Engine Fuel (Includes all amendments and changes 12/24/2025).

D4626-23

Standard Practice for Calculation of Gas Chromatographic Response Factors

D4307-17(2021)

Standard Practice for Preparation of Liquid Blends for Use as Analytical Standards

D4057-22

Standard Practice for Manual Sampling of Petroleum and Petroleum Products

D3700-26

Standard Practice for Obtaining LPG Samples Using a Floating Piston Cylinder

D2421-21e1

Standard Practice for Interconversion of Analysis of C5 and Lighter Hydrocarbons to Gas-Volume, Liquid-Volume, or Mass Basis (Includes all amendments and changes 6/16/2021).

D86-23ae2

Standard Test Method for Distillation of Petroleum Products and Liquid Fuels at Atmospheric Pressure (Includes all amendments and changes 11/4/2024).

D6300-26

Standard Practice for Determination of Precision and Bias Data for Use in Test Methods for Petroleum Products, Liquid Fuels, and Lubricants

D5599-22

Standard Test Method for Determination of Oxygenates in Gasoline by Gas Chromatography and Oxygen Selective Flame Ionization Detection

D5191-22

Standard Test Method for Vapor Pressure of Petroleum Products and Liquid Fuels (Mini Method)

D4815-22

Standard Test Method for Determination of MTBE, ETBE, TAME, DIPE, tertiary-Amyl Alcohol and C1 to C4 Alcohols in Gasoline by Gas Chromatography