ASTM D7168-21 - 15.12.2021
 
Significance and Use

5.1?This test method has not been evaluated for all possible matrices. Test method suitability should be determined on specific waters of interest.

 
1. Scope

1.1?This test method describes a solid phase extraction (SPE) procedure to separate 99Tc from environmental water (non-process-related or effluent water samples). Technetium-99 beta activity is measured by liquid scintillation spectrometry.

1.2?This test method is designed to measure 99Tc in the range of approximately 0.037 Bq/L (1.0 pCi/L) or greater for a one litre sample.

1.3?This test method has been used successfully with tap water. It is the users responsibility to ensure the validity of this test method for samples larger than 1 L and for waters of untested matrices.

1.4?Technetium-99 alternatively can be determined in water samples using Practice D8026.

1.5?The values stated in SI units are to be regarded as standard. The values given in parentheses are provided for information only and are not considered standard.

1.6?This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. For specific hazard statements, see Section 9.

1.7?This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

 
2. Referenced Documents

D4448-01(2019)

Standard Guide for Sampling Ground-Water Monitoring Wells

D5847-22

Standard Practice for Writing Quality Control Specifications for Standard Test Methods for Water Analysis

D6001-05

Standard Guide for Direct-Push Groundwater Sampling for Environmental Site Characterization

D7282-24

Standard Practice for Setup, Calibration, and Quality Control of Instruments Used for Radioactivity Measurements

D7902-24

Standard Terminology for Radiochemical Analyses

D8026-16

Standard Practice for Determination of Tc-99 in Water by Inductively Coupled Plasma Mass Spectrometry (ICP-MS) (Withdrawn 2025)

D1129-24

Standard Terminology Relating to Water

D1193-24

Standard Specification for Reagent Water

D2777-21

Standard Practice for Determination of Precision and Bias of Applicable Test Methods of Committee D19 on Water

D3370-25

Standard Practices for Sampling Water from Flowing Process Streams