ASTM E1333-22 - 1.8.2022
 
Significance and Use

4.1Significance and Use:

4.1.1Limitations on formaldehyde concentrations in air have been established for some building products permanently installed in manufactured and conventional homes. This test method provides a standard means of testing typical product sizes, such as 1.2 m by 2.4 m (4 ft by 8 ft) sheets, at product loadings consistent with product end use.

4.2Summary of Test Method:

4.2.1This test method incorporates a chamber of 22 m3 (800 ft3) minimum size to evaluate formaldehyde concentrations in air and emission rates from building products over a specified duration of time. This test method employs a single set of environmental conditions but different product loading ratios to assess formaldehyde concentrations in air and emission rates from certain wood products. Conditions controlled in the procedure are as follows:

4.2.1.1Conditioning of specimens prior to testing,

4.2.1.2Exposed surface area of the specimens in the test chamber,

4.2.1.3Test chamber temperature and relative humidity,

4.2.1.4Number of air changes per hour, and

4.2.1.5Air circulation within the chamber.

4.2.1.6At the end of a 16 to 20-h period in the test chamber, the air is sampled and the concentration of formaldehyde in air and emission rate are determined.

Note 3:Care must be exercised in the extension of the results to formaldehyde concentrations in air and emission rates from products under different conditions of air change rate or loading ratio, or both.

 
1. Scope

1.1This test method measures the formaldehyde concentration in air and emission rate from wood products containing formaldehyde under conditions designed to simulate product use (see 11.5 and Note 9). The concentration in air and emission rate is determined in a large chamber under specific test conditions of temperature and relative humidity. The general procedures are also intended for testing product combinations at product-loading ratios and at air-exchange rates typical of the indoor environment (1).2 The products tested, the loading ratios and the air exchange rates employed are described in the test report.

1.2This test method determines the average formaldehyde concentration in air and emission rate from a number of large size samples. The average concentration and emission rate reported, thus, will not provide information on higher or lower emitting panels in the test lot.

1.3This method is primarily used for testing newly manufactured panel products that are shipped for testing either seal-wrapped in polyethylene or with waster sheets, or with both. When this test method is used for evaluating other than newly manufactured panel products (after original application, installation or use), the method of packaging and shipping the product for testing shall be described in the test report.

1.4The quantity of formaldehyde in the air sample taken from the chamber is determined by an adaptation of the National Institute for Occupational Safety and Health (NIOSH) chromotropic acid test procedure. If another analytical procedure is used to determine the quantity of formaldehyde in the air sample, that procedure shall give results of equivalent or greater accuracy and precision than the adapted chromotropic acid procedure. Detailed procedures based on acetylacetone, pararosaniline (see Test Method D5221), 2,4-dinitrophenylhydrazine (DNPH) (see Test Method D5197) and 3-methyl-2-benzothiazoline (MBTH) (see Test Method D5014) have been found to give results equivalent or greater in accuracy and precision than chromotropic acid. The test report shall note the analytical procedure employed.

Note 1:3 The chromotropic acid analytical procedure described in this test method is applicable for testing urea-formaldehyde bonded wood products. According to NIOSH (4th Edition, 8/15/94), the low end of the working range for the chromotropic acid analytical procedure is 0.02 ppm. A more sensitive analytical procedure is recommended for testing wood panel products where formaldehyde concentrations in air are anticipated to be at or below this level. DNPH is recognized as such a method.

1.5This test method is used to determine compliance with requirements such as those established for building materials by the U.S. Department of Housing and Urban Development (HUD) Rules and Regulations, HUD 24 CFR 3280, for manufactured housing, by Minnesota Statutes Section 144.495, Environmental Protection Agency Formaldehyde Emission Standards for Composite Wood Products, EPA TSCA Title VI 40 CFR Section 770, and California Air Resources Board (CARB), California Code of Regulations sections 93120-93120.12, title 17, Airborne Toxic Control Measure to Reduce Formaldehyde Emissions from Composite Wood Products. Measurement results are also used for comparing concentrations in air and emission rates from different wood products (2) and for determining compliance with product standards.

1.6This test method is not designed for determining general organic emissions from all indoor materials and products.

Note 2:ASTM Committee D22 has developed Guide D5116 which describes small-scale environmental equipment and techniques suitable for determining organic emissions and emission rates from materials and products used indoors.

1.7The values stated in SI units are to be regarded as standard. The values given in parentheses are mathematical conversions to inch-pound units that are provided for information only and are not considered standard.

1.8This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. For specific hazard statements, see Section 7.

1.9This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

 
2. Referenced Documents

D5014-94(2000)e1

Standard Test Method for Measurement of Formaldehyde in Indoor Air (Passive Sampler Methodology) (Withdrawn 2006)

E337-15(2023)

Standard Test Method for Measuring Humidity with a Psychrometer (the Measurement of Wet- and Dry-Bulb Temperatures)

E220-25

Standard Test Method for Calibration of Thermocouples by Comparison Techniques

D3195-90(1998)e1

Standard Practice for Rotameter Calibration

D5221-92

Standard Test Method for Continuous Measurement of Formaldehyde in Air (Withdrawn 1997)

D5116-25

Standard Guide for Small-Scale Environmental Chamber Determinations of Organic Emissions from Indoor Materials/Products

ANSI?A208.2–2009

Medium Density Fiberboard (MDF) for Interior Applications

E741-24

Standard Test Method for Determining Air Change in a Single Zone by Means of a Tracer Gas Dilution

HUD?24?CFR?3280

Manufactured Home Construction and Safety Standards, 24, CFR 3280, Federal Register, Vol 49, No. 155, August 8, 1984

ANSI/HPVA HP-1-09

Hardwood and Decorative Plywood

ANSI?A208.1–2009

Particleboard

E77-14(2021)

Standard Test Method for Inspection and Verification of Thermometers

D5197-21

Standard Test Method for Determination of Formaldehyde and Other Carbonyl Compounds in Air (Active Sampler Methodology)