ASTM G111-21a - 1.11.2021
 
Significance and Use

5.1?Autoclave tests are commonly used to evaluate the corrosion performance of metallic and non-metallic materials under simulated HP and HTHP service conditions. Examples of service environments in which HP and HTHP corrosion tests have been used include chemical processing, petroleum production and refining, food processing, pressurized cooling water, electric power systems, and aerospace propulsion.

5.2?For the applications of corrosion testing listed in 5.1, the service environment involves handling corrosive and potentially hazardous media under conditions of high pressure or high temperature, or both. The temperature and pressure, among other parameters, usually drive the composition and properties of the aqueous phase and, hence, the severity of the corrosion process. Consequently, the laboratory evaluation of corrosion severity cannot be performed in conventional low pressure glassware without making potentially invalid assumptions as to the potential effects of high temperature and pressure on corrosion severity.

5.3?Therefore, there is a substantial need to provide standardized methods by which corrosion testing can be performed under HP and HTHP. In many cases, however, the standards used for exposure of specimens in conventional low-pressure glassware experiments cannot be followed due to the limitations of access, volume, and visibility arising from the construction of high-pressure test cells. This guide refers to existing corrosion standards and practices, as applicable, and then goes further in areas in which specific guidelines for performing HP and HTHP corrosion testing are needed.

 
1. Scope

1.1?This guide covers procedures, specimens, and equipment for conducting laboratory corrosion tests on metallic materials under conditions of high pressure (HP) or the combination of high temperature and high pressure (HTHP). See 3.2 for definitions of high pressure and temperature.

1.2?The procedures and methods in this guide are applicable for conducting mass loss corrosion, localized corrosion, and electrochemical tests as well as for use in environmentally induced cracking tests that need to be conducted under HP or HTHP conditions.

1.3?The primary purpose for this guide is to promote consistency of corrosion test results. Furthermore, this guide will aid in the comparison of corrosion data between laboratories or testing organizations that utilize different equipment.

1.4?The values stated in SI units are to be regarded as standard. The values given in parentheses after SI units are provided for information only and are not considered standard.

1.5?This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.

1.6?This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

 
2. Referenced Documents

G39-99(2021)

Standard Practice for Preparation and Use of Bent-Beam Stress-Corrosion Test Specimens

G46-21

Standard Guide for Examination and Evaluation of Pitting Corrosion

G59-23

Standard Test Method for Conducting Potentiodynamic Polarization Resistance Measurements

G78-20

Standard Guide for Crevice Corrosion Testing of Iron-Base and Nickel-Base Stainless Alloys in Seawater and Other Chloride-Containing Aqueous Environments

G106-89(2023)

Standard Practice for Verification of Algorithm and Equipment for Electrochemical Impedance Measurements

G38-01(2021)

Standard Practice for Making and Using C-Ring Stress-Corrosion Test Specimens

G34-23

Standard Test Method for Exfoliation Corrosion Susceptibility in 2XXX and 7XXX Series Aluminum Alloys (EXCO Test)

G49-85(2023)e1

Standard Practice for Preparation and Use of Direct Tension Stress-Corrosion Test Specimens (Includes all amendments and changes 11/13/2023).

G31-21

Standard Guide for Laboratory Immersion Corrosion Testing of Metals

E8-04

Standard Test Methods for Tension Testing of Metallic Materials

G30-22

Standard Practice for Making and Using U-Bend Stress-Corrosion Test Specimens

G15-08

Standard Terminology Relating to Corrosion and Corrosion Testing (Withdrawn 2010)

G1-03(2017)e1

Standard Practice for Preparing, Cleaning, and Evaluating Corrosion Test Specimens (Includes all amendments and changes 12/8/2017).

G3-14(2019)

Standard Practice for Conventions Applicable to Electrochemical Measurements in Corrosion Testing

G5-14(2021)

Standard Reference Test Method for Making Potentiodynamic Anodic Polarization Measurements