ASTM G170-06(2020)e1 - 1.11.2020
 
Significance and Use

5.1?Corrosion inhibitors continue to play a key role in controlling internal corrosion associated with oil and gas production and transportation. This results primarily from the industrys extensive use of carbon and low alloy steels, which, for many applications, are economic materials of construction that generally exhibit poor corrosion resistance. As a consequence, there is a strong reliance on inhibitor deployment for achieving cost-effective corrosion control, especially for treating long flowlines and main export pipelines (1).5

5.2?For multiphase flow, the aqueous-oil-gas interphases can take any of an infinite number of possible forms. These forms are delineated into certain classes of interfacial distribution called flow regimes. The flow regimes depend on the inclination of the pipe (that is, vertical or horizontal), flow rate (based on production rate), and flow direction (that is, upward or downward). The common flow regimes in vertical upward flow, vertical downward flow, and horizontal flow are presented in Figs. 1-3 respectively (2, 3).

5.14?To develop an inhibitor selection strategy, in addition to inhibitor efficiency, several other key performance factors need to be evaluated: (1) water/oil partitioning, (2) solubility, (3) emulsification tendency, (4) foaming tendency, (5) thermal stability, (6) toxicity, and (7) compatibility with other additives/materials.

 
1. Scope

1.1?This guide covers some generally accepted laboratory methodologies that are used for evaluating corrosion inhibitors for oilfield and refinery applications in well defined flow conditions.

1.2?This guide does not cover detailed calculations and methods, but rather covers a range of approaches which have found application in inhibitor evaluation.

1.3?Only those methodologies that have found wide acceptance in inhibitor evaluation are considered in this guide.

1.4?This guide is intended to assist in the selection of methodologies that can be used for evaluating corrosion inhibitors.

1.5?The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.

1.6?This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory requirements prior to use.

1.7?This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

 
2. Referenced Documents

G111-21a

Standard Guide for Corrosion Tests in High Temperature or High Pressure Environment, or Both (Includes all amendments and changes 12/28/2021).

G106-89(2023)

Standard Practice for Verification of Algorithm and Equipment for Electrochemical Impedance Measurements

ISO 6614

Petroleum Products -- Determination of Water Separability of Petroleum Oils and Synthetic Fluids

D1141-98(2021)

Standard Practice for Preparation of Substitute Ocean Water

D4410-16

Terminology for Fluvial Sediment

G1-03(2017)e1

Standard Practice for Preparing, Cleaning, and Evaluating Corrosion Test Specimens (Includes all amendments and changes 12/8/2017).

G3-14(2019)

Standard Practice for Conventions Applicable to Electrochemical Measurements in Corrosion Testing

G5-14(2021)

Standard Reference Test Method for Making Potentiodynamic Anodic Polarization Measurements

G15-08

Standard Terminology Relating to Corrosion and Corrosion Testing (Withdrawn 2010)

G16-13(2019)

Standard Guide for Applying Statistics to Analysis of Corrosion Data

G31-21

Standard Guide for Laboratory Immersion Corrosion Testing of Metals

G46-21

Standard Guide for Examination and Evaluation of Pitting Corrosion

G59-23

Standard Test Method for Conducting Potentiodynamic Polarization Resistance Measurements

G96-90(2018)

Standard Guide for Online Monitoring of Corrosion in Plant Equipment (Electrical and Electrochemical Methods)

G102-23

Standard Practice for Calculation of Corrosion Rates and Related Information from Electrochemical Measurements

NACE-TM0196

Standard Test Method Chemical Resistance of Polymeric Materials by Periodic Evaluation, Houston, TX, NACE International Publication, Item No. 21226, 1996