ASTM G185-06(2012) - 1.11.2012
 
Significance and Use

5.1 Selection of corrosion inhibitor for oil field and refinery applications involves qualification of corrosion inhibitors in the laboratory (see Guide G170). Field conditions should be simulated in the laboratory in a fast and cost-effective manner (1).4

5.2 Oil field corrosion inhibitors should provide protection over a range of flow conditions from stagnant to that found during typical production conditions. Not all inhibitors are equally effective over this range of conditions so that is important for a proper evaluation of inhibitors to test the inhibitors using a range of flow conditions.

5.3 The RCE is a compact and relatively inexpensive approach to obtaining varying hydrodynamic conditions in a laboratory apparatus. It allows electrochemical methods of estimating corrosion rates on the specimen and produces a uniform hydrodynamic state across the metal test surface. (2-21)

5.4 In this practice, a general procedure is presented to obtain reproducible results using RCE to simulate the effects of different types of coupon materials, inhibitor concentrations, oil, gas and brine compositions, temperature, pressure, and flow. Oil field fluids may often contain sand. This practice does not cover erosive effects that occur when sand is present.

 
1. Scope

1.1 This practice covers a generally accepted procedure to use the rotating cylinder electrode (RCE) for evaluating corrosion inhibitors for oil field and refinery applications in defined flow conditions.

1.2 The values stated in SI units are to be regarded as standard. The values given in parentheses are for information only.

1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

 
2. Referenced Documents

G170-06(2020)e1

Standard Guide for Evaluating and Qualifying Oilfield and Refinery Corrosion Inhibitors in the Laboratory (Includes all amendments and changes 12/10/2020).

G5-14(2021)

Standard Reference Test Method for Making Potentiodynamic Anodic Polarization Measurements

G15-08

Standard Terminology Relating to Corrosion and Corrosion Testing (Withdrawn 2010)

G16-13(2019)

Standard Guide for Applying Statistics to Analysis of Corrosion Data

G31-21

Standard Guide for Laboratory Immersion Corrosion Testing of Metals

G111-21a

Standard Guide for Corrosion Tests in High Temperature or High Pressure Environment, or Both (Includes all amendments and changes 12/28/2021).

G106-89(2023)

Standard Practice for Verification of Algorithm and Equipment for Electrochemical Impedance Measurements

G102-23

Standard Practice for Calculation of Corrosion Rates and Related Information from Electrochemical Measurements

G96-90(2018)

Standard Guide for Online Monitoring of Corrosion in Plant Equipment (Electrical and Electrochemical Methods)

G59-23

Standard Test Method for Conducting Potentiodynamic Polarization Resistance Measurements

D1141-98(2021)

Standard Practice for Preparation of Substitute Ocean Water

D4410-16

Terminology for Fluvial Sediment

G1-03(2017)e1

Standard Practice for Preparing, Cleaning, and Evaluating Corrosion Test Specimens (Includes all amendments and changes 12/8/2017).

G46-21

Standard Guide for Examination and Evaluation of Pitting Corrosion

G3-14(2019)

Standard Practice for Conventions Applicable to Electrochemical Measurements in Corrosion Testing