ASTM C1267-00 - 10.1.2000
 
1. Scope

1.1 This test method, commonly referred to as the Modified Davies and Gray technique, covers the titration of uranium in product, fuel, and scrap materials after the material is dissolved. The test method is versatile and has been ruggedness tested. With appropriate sample preparation, this test method can give precise and unbiased uranium assays over a wide variety of material types (1, 2). Details of the titration procedure in the presence of plutonium with appropriate modifications are given in Test Method C1204.

1.2 Uranium levels titrated are usually 20 to 50 mg, but up to 200 mg uranium can be titrated using the reagent volumes stated in this test method.

1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. For specific safeguard and safety precaution statements, see Section 4.

 
2. Referenced Documents

C1346-19

Standard Practice for Dissolution of UF6 from P-10 Tubes

C1128-23

Standard Guide for Preparation of Working Reference Materials for Use in Analysis of Nuclear Fuel Cycle Materials

C1204-14(2023)

Standard Test Method for Uranium in Presence of Plutonium by Iron(II) Reduction in Phosphoric Acid Followed by Chromium(VI) Titration

C799-19

Standard Test Methods for Chemical, Mass Spectrometric, Spectrochemical, Nuclear, and Radiochemical Analysis of Nuclear-Grade Uranyl Nitrate Solutions

C696-19

Standard Test Methods for Chemical, Mass Spectrometric, and Spectrochemical Analysis of Nuclear-Grade Uranium Dioxide Powders and Pellets

C1347-08(2023)

Standard Practice for Preparation and Dissolution of Uranium Materials for Analysis

CRM 112A

Uranium Metal Standard

SRM 136e

Potassium Dichromate (Oxidimetric Standard)