ASTM C1301-95(2009)e1 - 1.6.2009
 
Significance and Use

The presence and concentration of elements in lime and limestone is important in determining product quality and its suitability for various uses. This test method provides a means of measuring the major and trace element concentration in lime and limestone.

 
1. Scope

1.1 The following test method covers the use of inductively coupled plasma-atomic emission spectroscopy (ICP) and atomic absorption spectroscopy (AA) in the analysis of major and trace elements in limestone and lime (calcined limestone).

1.2 Table 1 lists some of the elements that can be analyzed by this test method and the preferred wavelengths. Also see U.S. EPA Methods 200.7 and 200.9.

1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.

1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

TABLE 1 Elements and Some Suggested WavelengthsA

Major ElementsICP Wavelength, nmAA Wavelength, nm

Calcium

317.933 (315.887)B

422.7

Magnesium

279.079 (285.213)

285.2

Silicon

251.611 (288.160)

251.6

Aluminum

308.215 (309.271)

309.3

Iron

259.940

248.3

Manganese

257.610

279.5

Sodium

588.995 (589.59)

589.0

Potassium

766.491

766.5

Phosphorus

214.914 (213.618)

...C

Strontium

421.552

460.7

Trace Elements

ICP Wavelength, nm

AA Wavelength, nm

Antimony

206.833

217.6

Arsenic

193.696

193.7

Barium

455.403 (493.409)

553.6

Beryllium

313.042

234.9

Boron

249.773

249.8

Cadmium

226.502 (228.80)

228.8

Chromium

267.716 (205.552)

357.9

Cobalt

228.616

240.7 (242.5)

Copper

324.754

324.8

Lead

220.353

217.0 (283.3)

Molybdenum

202.030 (203.844)

313.3

Nickel

231.604 (221.647)

232.0

Selenium

196.090

196.0

Silver

328.068

328.1

Sulfur

180.731 (180.669)

...C

Thallium

190.864

276.8

Tin

189.989

235.5 (286.3)

Vanadium

292.402

318.4

Zinc

213.856 (202.551)

213.9

A The suggested wavelengths may vary for your particular instrument.

B Numbers in parentheses are alternate wavelengths.

C Not recommended or not used.

 
2. Referenced Documents

C51-26

Standard Terminology Relating to Lime and Limestone (as Used by the Industry)

E135-26a

Standard Terminology Relating to Analytical Chemistry for Metals, Ores, and Related Materials (Includes all amendments and changes 8/6/2026).

E1479-24

Standard Practice for Describing and Specifying Inductively Coupled Plasma Atomic Emission Spectrometers

D1193-24

Standard Specification for Reagent Water

E863-98

Standard Practice for Describing Flame Atomic Absorption Spectroscopy Equipment