ASTM D4590-22 - 1.11.2022
 
Significance and Use

5.1?This test method is suitable for determining the quantity of TBC inhibitor, both for the protection against polymerization while in transit and storage, and for internal quality control.

 
1. Scope

1.1?This test method is applicable to the determination of residual 4-tertiary-butylcatechol (TBC) in styrene monomer or AMS in the 1 mg/kg to 100 mg/kg range.

1.2?In determining the conformance of the test results using this method to applicable specifications, results shall be rounded off in accordance with the rounding-off method of Practice E29. The limit of detection is 0.2 mg/kg while the limit of quantitation is 0.8 mg/kg based on the ILS data in Table 1.

1.3?The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.

1.4?This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. For specific statements on hazards, see Section 9.

1.5?This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

 
2. Referenced Documents

D6809-20a

Standard Guide for Quality Control and Quality Assurance Procedures for Aromatic Hydrocarbons and Related Materials (Includes all amendments and changes 10/20/2020).

D3437-15(2022)

Standard Practice for Sampling and Handling Liquid Cyclic Products

D1193-06(2018)

Standard Specification for Reagent Water

E29-22

Standard Practice for Using Significant Digits in Test Data to Determine Conformance with Specifications

E691-23

Standard Practice for Conducting an Interlaboratory Study to Determine the Precision of a Test Method

D4790-23

Standard Terminology of Aromatic Hydrocarbons and Related Chemicals