ASTM D4692-01(2017) - 1.12.2017
 
Significance and Use

5.1 In the design and operation of reverse osmosis and nanofiltration installations, it is important to predict the CaSO4, SrSO4, and BaSO4 scaling properties of the concentrate stream. Because of the increase in total dissolved solids and the increase in concentration of the scaling salts, the scaling properties of the concentrate stream will be quite different from those of the feed solution. This practice permits the calculation of the scaling potential for the concentrate stream from the feed water analyses and the reverse osmosis or nanofiltration operating parameters.

5.2 Scaling by CaSO4, SrSO4, and BaSO4 will adversely affect the reverse osmosis or nanofiltration performance. This practice gives various procedures for the prevention of scaling.

 
1. Scope

1.1 This practice covers the calculation and adjustment of calcium, strontium, and barium sulfates for the concentrate stream of a reverse osmosis or nanofiltration system. The calculations are used to determine the need for scale control in the operation and design of reverse osmosis and nanofiltration installations. This practice is applicable for all types of reverse osmosis devices (tubular, spiral wound, and hollow fiber) and nanofiltration devices.

1.2 This practice is applicable to both brackish waters and seawaters.

1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.

1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

 
2. Referenced Documents

D4195-23

Standard Guide for Water Analysis for Reverse Osmosis and Nanofiltration Application

D4194-23

Standard Test Methods for Operating Characteristics of Reverse Osmosis and Nanofiltration Devices

D3352-15

Standard Test Method for Strontium Ion in Brackish Water, Seawater, and Brines

D1129-13(2020)e2

Standard Terminology Relating to Water (Includes all amendments and changes 2/14/2024).

D516-22

Standard Test Method for Sulfate Ion in Water

D511-14(2021)e1

Standard Test Methods for Calcium and Magnesium In Water (Includes all amendments and changes 12/6/2021).

D4382-18

Standard Test Method for Barium in Water, Atomic Absorption Spectrophotometry, Graphite Furnace

D6161-19

Standard Terminology Used for Microfiltration, Ultrafiltration, Nanofiltration, and Reverse Osmosis Membrane Processes