ASTM D4007-02(2006) - 1.11.2006
 
Significance and Use

The water and sediment content of crude oil is significant because it can cause corrosion of equipment and problems in processing. A determination of water and sediment content is required to measure accurately net volumes of actual oil in sales, taxation, exchanges, and custody transfers.

 
1. Scope

1.1 This test method describes the laboratory determination of water and sediment in crude oils by means of the centrifuge procedure. This centrifuge method for determining water and sediment in crude oils is not entirely satisfactory. The amount of water detected is almost always lower than the actual water content. When a highly accurate value is required, the revised procedures for water by distillation, Test Method D 4006 (API MPMS Chapter 10.2) (), and sediment by extraction, Test Method D 473 (API MPMS Chapter 10.1), shall be used. Note 1Test Method D 4006 (API MPMS Chapter 10.2) has been determined to be the preferred and most accurate method for the determination of water.

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1.2 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.

This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. For specific precautionary statements, see 6.1.

 
2. Referenced Documents

D473-22

Standard Test Method for Sediment in Crude Oils and Fuel Oils by the Extraction Method

D665-25

Standard Test Method for Rust-Preventing Characteristics of Inhibited Mineral Oil in the Presence of Water

D4177-22e1

Standard Practice for Automatic Sampling of Petroleum and Petroleum Products (Includes all amendments and changes 3/24/2023).

D4928-26

Standard Test Method for Water in Crude Oils by Coulometric Karl Fischer Titration

D1796-22

Standard Test Method for Water and Sediment in Fuel Oils by the Centrifuge Method (Laboratory Procedure)

E969-02(2024)

Standard Specification for Glass Volumetric (Transfer) Pipets

D95-23e1

Standard Test Method for Water in Petroleum Products and Bituminous Materials by Distillation (Includes all amendments and changes 10/25/2024).

D4006-22

Standard Test Method for Water in Crude Oil by Distillation

D4057-22

Standard Practice for Manual Sampling of Petroleum and Petroleum Products

D5854-25

Standard Practice for Mixing and Handling of Liquid Samples of Petroleum and Petroleum Products