ASTM D4130-08 - 15.11.2008
 
Significance and Use

The determination of sulfate and other dissolved constituents is important in identifying the source of brines produced during the drilling and production phases of crude oil or natural gas.

 
1. Scope

1.1 This test method covers the turbidimetric determination of sulfate ion in brackish water, seawater, and brines. It has been used successfully with synthetic brine grade waters; however, it is the user's responsibility to ensure the validity of this test method to other matrices.

1.2 This test method is applicable to waters having an ionic strength greater than 0.65 mol/L and a sulfate ion concentration greater than 25 mg/L. A concentration less than 25 mg/L sulfate can be determined by using a standard addition method.

1.3 For brines having an ionic strength of less than 0.65 mol/L, refer to Test Methods D 516.

1.4 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.

1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

 
2. Referenced Documents

D3370-25

Standard Practices for Sampling Water from Flowing Process Streams

D5810-96(2026)

Standard Guide for Spiking into Aqueous Samples

D5847-22

Standard Practice for Writing Quality Control Specifications for Standard Test Methods for Water Analysis

E275-08(2022)

Standard Practice for Describing and Measuring Performance of Ultraviolet and Visible Spectrophotometers

E2251-14(2021)

Standard Specification for Liquid-in-Glass ASTM Thermometers with Low-Hazard Precision Liquids

D2777-21

Standard Practice for Determination of Precision and Bias of Applicable Test Methods of Committee D19 on Water

D1193-24

Standard Specification for Reagent Water

D516-22

Standard Test Method for Sulfate Ion in Water

D1129-24

Standard Terminology Relating to Water