ASTM D4191-97 - 10.12.1997
 
1. Scope

1.1 This test method covers the determination of low amounts of sodium in waters having low solids content. The applicable range of this test method is from 0.20 to 3.0 mg/L when using the 589.6-nm resonance line. This range may be extended upward by dilution of an appropriate aliquot of sample or by use of the less-sensitive 330.2-nm resonance line. Many workers have found that this test method is reliable for sodium levels to 0.005 mg/L, but use of this test method at this low level is dependent on the configuration of the aspirator and nebulizer system available in the atomic absorption spectrophotometer as well as the experience and skill of the analyst. The precision and bias data presented are insufficient to justify use of this test method in the 0.005 to 0.20-mg/L range.

1.2 This test method has been used successfully with spiked reagent water. It is the analyst's responsibility to assure the validity of the test method to other low dissolved solids matrices.

1.3 This standard does not purport to address all of the safety problems, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

 
2. Referenced Documents

D1193-24

Standard Specification for Reagent Water

D4841-88(2018)

Standard Practice for Estimation of Holding Time for Water Samples Containing Organic and Inorganic Constituents

D2777-21

Standard Practice for Determination of Precision and Bias of Applicable Test Methods of Committee D19 on Water

D1129-24

Standard Terminology Relating to Water

D1066-18(2025)

Standard Practice for Sampling Steam

D3561-16(2021)e1

Standard Test Method for Lithium, Potassium, and Sodium Ions in Brackish Water, Seawater, and Brines by Atomic Absorption Spectrophotometry (Includes all amendments and changes 12/22/2021).

D3370-25

Standard Practices for Sampling Water from Flowing Process Streams

D5847-22

Standard Practice for Writing Quality Control Specifications for Standard Test Methods for Water Analysis

D5810-96(2026)

Standard Guide for Spiking into Aqueous Samples