ASTM D6514-03(2019)e1 - 1.5.2019
 
Significance and Use

5.1 Degradation of fluid lubricants because of oxidation or thermal breakdown can result in fluid thickening or in the formation of acids or insoluble solids and render the fluid unfit for further use as a lubricant.

5.2 This test method can be used for estimating the oxidation stability of oils. It can function as a formulation screening tool, specification requirement, quality control measurement, or as a means of estimating remaining service life. It shall be recognized, however, that correlation between results of this test method and the oxidation stability of an oil in field service can vary markedly with field service conditions and with various oils.

5.3 This test method is designed to compliment Test Method D5846 and is intended for evaluation of fluids which do not degrade significantly within a reasonable period of time at 135 °C.

 
1. Scope

1.1 This test method covers a procedure for evaluating the oxidation of inhibited lubricants in the presence of air, copper, and iron metals.

1.2 This test method was developed and is used to evaluate the high temperature oxidation stability and deposit forming tendency of oils for steam and gas turbines. It has been used for testing other lubricants made with mineral oil and synthetic basestocks for compressors, hydraulic pumps, and other applications, but these have not been used in cooperative testing.

1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.

1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  Identified hazardous chemicals are listed in Section 7. Before using this test method, refer to suppliers' safety labels, Material Safety Data Sheets and other technical literature.

1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

 
2. Referenced Documents

IP 2546

Practice for Sampling of Petroleum Products; Alternate to Practice

Oxidation Cell Varnish Standard

D664-18e2

Standard Test Method for Acid Number of Petroleum Products by Potentiometric Titration (Includes all amendments and changes 1/4/2019).

D445-23

Standard Test Method for Kinematic Viscosity of Transparent and Opaque Liquids (and Calculation of Dynamic Viscosity)

B1-13(2018)

Standard Specification for Hard-Drawn Copper Wire

A510-08

Standard Specification for General Requirements for Wire Rods and Coarse Round Wire, Carbon Steel

D974-22

Standard Test Method for Acid and Base Number by Color-Indicator Titration

D5846-07(2017)

Standard Test Method for Universal Oxidation Test for Hydraulic and Turbine Oils Using the Universal Oxidation Test Apparatus

D4871-11(2022)

Standard Guide for Universal Oxidation/Thermal Stability Test Apparatus

D4057-22

Standard Practice for Manual Sampling of Petroleum and Petroleum Products

D3339-21

Standard Test Method for Acid Number of Petroleum Products by Semi-Micro Color Indicator Titration

BS 1829

Specification for Carbon Steel, alternate to Specification

D943-20

Standard Test Method for Oxidation Characteristics of Inhibited Mineral Oils