ASTM D7213-12e1 - 1.2.2013
 
Significance and Use

5.1 The boiling range distribution of light and medium petroleum distillate fractions provides an insight into the composition of feed stocks and products related to petroleum refining process, This gas chromatographic determination of boiling range can be used to replace conventional distillation methods for control of refining operations. This test method can be used for product specification testing with the mutual agreement of interested parties.

5.2 This test method extends the scope of boiling range determination by gas chromatography to include light and medium petroleum distillate fractions beyond the scope of Test Method D2887 (538°C) and below Test Method D6352 (700°C).

5.3 Boiling range distributions obtained by this test method are theoretically equivalent to those obtained by true boiling point (TBP) distillation (see Test Method D2892). They are not equivalent to results from low efficiency distillation such as those obtained with Test Method D86 or D1160.

 
1. Scope

1.1 This test method covers the determination of the boiling range distribution of petroleum products. This test method is applicable to petroleum distillates having an initial boiling point greater than 100°C and a final boiling point less than 615°C at atmospheric pressure as measured by this test method.

1.2 The test method is not applicable for analysis of petroleum distillates containing low molecular weight components (for example, naphthas, reformates, gasolines, crude oils). Materials containing heterogeneous components (for example, alcohols, ethers, acids or esters) or residue are not to be analyzed by this test method. See Test Methods D3710, D2887, D6352, or D5307.

1.3 This test method uses the principles of simulated distillation methodology.

1.4 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.

1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

 
2. Referenced Documents

D2892-25

Standard Test Method for Distillation of Crude Petroleum (15-Theoretical Plate Column)

D4626-23

Standard Practice for Calculation of Gas Chromatographic Response Factors

D6352-24

Standard Test Method for Boiling Range Distribution of Petroleum Distillates in Boiling Range from 174 ?C to 700 ?C by Gas Chromatography

D7096-25

Standard Test Method for Determination of the Boiling Range Distribution of Gasoline by Wide-Bore Capillary Gas Chromatography

D7169-23

Standard Test Method for Boiling Point Distribution of Samples with Residues Such as Crude Oils and Atmospheric and Vacuum Residues by High Temperature Gas Chromatography

E355-96(2021)e1

Standard Practice for Gas Chromatography Terms and Relationships (Includes all amendments and changes 4/28/2021).

E594-96(2026)

Standard Practice for Testing Flame Ionization Detectors Used in Gas or Supercritical Fluid Chromatography

E1510-95(2021)

Standard Practice for Installing Fused Silica Open Tubular Capillary Columns in Gas Chromatographs

D86-23ae2

Standard Test Method for Distillation of Petroleum Products and Liquid Fuels at Atmospheric Pressure (Includes all amendments and changes 11/4/2024).

D1160-24

Standard Test Method for Distillation of Petroleum Products at Reduced Pressure

D2887-24

Standard Test Method for Boiling Range Distribution of Petroleum Fractions by Gas Chromatography